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Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine
Shi, Jinbiao; Zhang, Jianling; Liang, Tongling; Tan, Dongxing; Tan, Xiuniang; Wan, Qiang; Cheng, Xiuyan; Zhang, Bingxing; Han, Buxing; Liu, Lifei; Zhang, Fanyu; Chen, Gang
2019-08-28
Source PublicationACS APPLIED MATERIALS & INTERFACES
ISSN1944-8244
Volume11Issue:34Pages:30953-30958
AbstractMetal-organic frameworks (MOFs) have attracted increased research attention in photocatalysis due to their great potential in light harvest and conversion. However, the organic transformations as photocatalyzed by MOFs under mild conditions yet remain a challenge. Herein, three bipyridylcontaining cadmium-organic frameworks Cd(dcbpy) (dcbpy = 2,2'-bipyridine-5,5'-dicarboxylate), Cd(bdc)(bpy) (bdc = 1,4-benzenedicarboxylate; bpy = 2,2'-bipyridyl), and Cd(bdc)(2Me-bpy) (2Me-bpy = 4,4'-dimethyl-2,2'-bipyridyl) were synthesized for the first time. The bpy-containing Cd-MOFs have strong light harvest abilities and suitable photocatalysis energy potentials, making them highly active and selective for the photo-oxidation of benzylamine to N-benzylbenzaldimine under mild conditions, i.e., using atmospheric air as oxidant, at room temperature, and in the absence of any photosensitizer or cocatalyst. It provides an efficient, economical, and green way for the direct oxidation of amines to produce imines.
DOI10.1021/acsami.9b09879
Indexed BySCI
Language英语
WOS IDWOS:000484073400048
EI Accession Number1944-8252
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82627
Collection中国科学院化学研究所
AffiliationChinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Shi, Jinbiao,Zhang, Jianling,Liang, Tongling,et al. Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(34):30953-30958.
APA Shi, Jinbiao.,Zhang, Jianling.,Liang, Tongling.,Tan, Dongxing.,Tan, Xiuniang.,...&Chen, Gang.(2019).Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine.ACS APPLIED MATERIALS & INTERFACES,11(34),30953-30958.
MLA Shi, Jinbiao,et al."Bipyridyl-Containing Cadmium-Organic Frameworks for Efficient Photocatalytic Oxidation of Benzylamine".ACS APPLIED MATERIALS & INTERFACES 11.34(2019):30953-30958.
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