ICCAS OpenIR
Synthesis, Fourier-transform Raman and infrared spectroscopic analysis, and crystal structure of (NiL)(2), (L = bis(2,4-dimethyldipyrrin-3-yl)methane)
Shan, XF; Yang, LY; Li, W; Chen, QQ; Wang, ZP; Hu, JM; Ma, JS
2004-07-01
Source PublicationJOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN1074-1542
Volume34Issue:7Pages:433-439
AbstractThe Ni(II) complex with bis(2,4-dimethyldipyrrin-3-yl) methane, (NiL)(2), has been synthesized and characterized by H-1-NMR, UV-Vis, FT-IR, FT-Raman, MS, and elemental analysis. X-ray diffraction analysis at room temperature indicates that the complex crystallizes in triclinic system, space group P - 1 with a = 11.344( 4), b = 12.703( 4), c = 14.936( 5) Angstrom, alpha = 87.017(6) degrees, beta = 75.379(5) degrees, gamma = 75.318(5)degrees, M-r = 826.31, V = 2014.5(11) Angstrom(3), Z = 2. The crystal structure of the title complex reveals that it is a dinuclear double-stranded helical entity. The ligands perform as tetradentate ligands and the ratio of Ni( II) to ligand is 2: 2. The central Ni( II) atom is tetracoordinated by four nitrogen donors of two ligands and the coordination geometry of Ni( II) can be considered as a distorted tetrahedron configuration. The IR and Raman spectral analysis, assignment, and discussion are presented.
KeywordSynthesis Crystal Structure Ni(Ii) Complex Dipyrrin Raman Spectroscopy Infrared Spectroscopy
Indexed BySCI
Language英语
WOS IDWOS:000222800700005
PublisherKLUWER ACADEMIC/PLENUM PUBL
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82564
Collection中国科学院化学研究所
Corresponding AuthorMa, JS
Affiliation1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China
2.Wuhan Univ, Dept Anal Measurement Sci, Wuhan 430072, Peoples R China
3.Harbin Engn Univ, Dept Chem Engn, Harbin 150001, Peoples R China
4.Biomarin Pharmaceut Inc, Novato, CA 94949 USA
Recommended Citation
GB/T 7714
Shan, XF,Yang, LY,Li, W,et al. Synthesis, Fourier-transform Raman and infrared spectroscopic analysis, and crystal structure of (NiL)(2), (L = bis(2,4-dimethyldipyrrin-3-yl)methane)[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,2004,34(7):433-439.
APA Shan, XF.,Yang, LY.,Li, W.,Chen, QQ.,Wang, ZP.,...&Ma, JS.(2004).Synthesis, Fourier-transform Raman and infrared spectroscopic analysis, and crystal structure of (NiL)(2), (L = bis(2,4-dimethyldipyrrin-3-yl)methane).JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,34(7),433-439.
MLA Shan, XF,et al."Synthesis, Fourier-transform Raman and infrared spectroscopic analysis, and crystal structure of (NiL)(2), (L = bis(2,4-dimethyldipyrrin-3-yl)methane)".JOURNAL OF CHEMICAL CRYSTALLOGRAPHY 34.7(2004):433-439.
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