ICCAS OpenIR
Synthesis, structure and polymer-incorporation of zirconium Schiff base: Catalysts bearing allyl substituent for ethylene polymerization
Chen, ZJ; Jin, GX; Hu, NH
2004-12-01
Source PublicationCHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN1001-4861
Volume20Issue:12Pages:1383-1389
AbstractGroup IV complexes of Schiff base bearing allyl substituent [R(N=CH-C6H3(3-R)O)(2)MCl2 (R=Allyl, R(=Pheny, M=Ti(6), M=Zr(7); R=tert-Butyl, R(=Allyl, M=Ti(8), M=Zr(9)) were prepared and characterized. Molecular structure of complex.: 7, shows that 7. is in a distorted octahedral coordination geometry around the Zr atom and two oxygen atoms are situated in trans position while two nitrogen atom's and two chlorine atoms are situated in cis position. Allyl groups: in 7 and 9 can be co-polymerized With styrene to for in pohmeiized'catalysts '(PSC1 and y PSC2). The complex 9 and -'corresponding polymerized catalyst (Pse2) exhibited high aciivities for ethylene polymerization in the presence of MMAO as co-catalyst. CCDC: 251659.
KeywordTitanium Zirconium Ethylene Polymerization Catalyst Polymerized Catalyst
Indexed BySCI
Language英语
WOS IDWOS:000225721000002
PublisherCHINESE CHEMICAL SOCIETY
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82460
Collection中国科学院化学研究所
Corresponding AuthorJin, GX
Affiliation1.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Chen, ZJ,Jin, GX,Hu, NH. Synthesis, structure and polymer-incorporation of zirconium Schiff base: Catalysts bearing allyl substituent for ethylene polymerization[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2004,20(12):1383-1389.
APA Chen, ZJ,Jin, GX,&Hu, NH.(2004).Synthesis, structure and polymer-incorporation of zirconium Schiff base: Catalysts bearing allyl substituent for ethylene polymerization.CHINESE JOURNAL OF INORGANIC CHEMISTRY,20(12),1383-1389.
MLA Chen, ZJ,et al."Synthesis, structure and polymer-incorporation of zirconium Schiff base: Catalysts bearing allyl substituent for ethylene polymerization".CHINESE JOURNAL OF INORGANIC CHEMISTRY 20.12(2004):1383-1389.
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