ICCAS OpenIR
Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups
Zou, JF; Cao, CG; Dong, JY; Hu, YL; Chung, TC
2004-10-22
Source PublicationMACROMOLECULAR RAPID COMMUNICATIONS
ISSN1022-1336
Volume25Issue:20Pages:1797-1804
AbstractCopolymerization of propylene and 1,4-divinyl-benzene was successfully performed by a MgCl2-supported TiCl4 catalyst, yielding isotactic poly(propylene) (i-PP) polymers containing a few pendant styrene groups. With a metalation reaction with butyllithium and a hydrochlorination reaction with dry hydrogen chloride, the pendant styrene groups were quantitatively transformed into benzyllithium and 1-chloroethylbenzene groups, respectively, which allowed the synthesis of i-PP-based graft copolymers by living anionic and atom transfer radical (ATRP) polymerization mechanisms.
KeywordCatalysts Copolymerization Graft Copolymers 1 4-divinylbenzene
DOI10.1002/marc.200400284
Indexed BySCI ; CCR
Language英语
WOS IDWOS:000224948200008
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82444
Collection中国科学院化学研究所
Corresponding AuthorDong, JY
Affiliation1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
3.Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
Recommended Citation
GB/T 7714
Zou, JF,Cao, CG,Dong, JY,et al. Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2004,25(20):1797-1804.
APA Zou, JF,Cao, CG,Dong, JY,Hu, YL,&Chung, TC.(2004).Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups.MACROMOLECULAR RAPID COMMUNICATIONS,25(20),1797-1804.
MLA Zou, JF,et al."Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups".MACROMOLECULAR RAPID COMMUNICATIONS 25.20(2004):1797-1804.
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