ICCAS OpenIR
Design and synthesis of a new nonlinear optical poly(phthalazinone ether ketone)
Lu, ZQ; Liu, YY; Qin, JG; Yang, Z; Ye, C
2004
Source PublicationREACTIVE & FUNCTIONAL POLYMERS
ISSN1381-5148
Volume61Issue:3Pages:379-386
AbstractThis paper reports a new nonlinear optical (NLO) poly(phthalazinone ether ketone) P1 with a high molar density (80%) of chromophore. It has been synthesized by Heck reaction between a brominated poly(phthalazinone ether ketone) P and the NLO chromophore 4. P1 exhibited excellent thermal properties and good solubility due to the presence of the kinked non-planar moiety.. phenyl phthalazinone, along the polymer backbones. DSC indicated that the glass transition temperature (T-g) of P1 was 188 degreesC, and TGA indicated that P1 was thermally stable up to 290 degreesC in both air and argon. The structures of P and P1 were characterized, and the poled films of P1 revealed a second-order nonlinear optical coefficient (d(33)) value of 16.9 pm/V by in situ second harmonic generation measurements at 1064 nm fundamental wavelength. (C) 2004 Elsevier B.V. All rights reserved.
KeywordNlo Poly(Phthalazinone Ether Ketone) Heck Reaction
DOI10.1016/j.reactfunctpolym.2004.07.001
Indexed BySCI
Language英语
WOS IDWOS:000225261800008
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82434
Collection中国科学院化学研究所
Corresponding AuthorQin, JG
Affiliation1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Ctr Mol Sci, Organ Solids Lab, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Lu, ZQ,Liu, YY,Qin, JG,et al. Design and synthesis of a new nonlinear optical poly(phthalazinone ether ketone)[J]. REACTIVE & FUNCTIONAL POLYMERS,2004,61(3):379-386.
APA Lu, ZQ,Liu, YY,Qin, JG,Yang, Z,&Ye, C.(2004).Design and synthesis of a new nonlinear optical poly(phthalazinone ether ketone).REACTIVE & FUNCTIONAL POLYMERS,61(3),379-386.
MLA Lu, ZQ,et al."Design and synthesis of a new nonlinear optical poly(phthalazinone ether ketone)".REACTIVE & FUNCTIONAL POLYMERS 61.3(2004):379-386.
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