ICCAS OpenIR
Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands
Yu, XY; Lu, SX; Jin, GX; Weng, LH
2004-01-30
Source PublicationINORGANICA CHIMICA ACTA
ISSN0020-1693
Volume357Issue:2Pages:361-366
AbstractThree mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands were synthesized and characterized by X-ray crystallography. The reactions of Ni(COD)(2)(COD=1,5-octadiene) with [(THF)(3)LiE2)C2B10H10Li(THF)](2) (E = S, Se) in THF in the presence of air in different ratios afforded the mono- and dinuclear nickel complexes of formulae Li(THF)(4)](2)[Ni(E2C2B10H10)(2)] (E=S, la; E=Se, 1b) and [Li(THF)(4)](2)[Ni-2(E(2)CZB(10)H(10))(3)] (E=S, 2a; E=Se, 2b). In 2a, two nickel atoms are connected by one chalcogen (eta(1),eta(2)-S2C2B10H10) bridging ligand with strong metal-metal interaction. Complex of formula (PPh3)(2)Ni(S2C2B10H10).0.5THF (3a) was also obtained from the reaction of (PPh3)(2)NiCl2 and [(THF)(3)LiS2C2B10H10Li(THF)](2). (C) 2003 Elsevier B.V. All rights reserved.
KeywordNickel Complexes Crystal Structures Dichalcogenolate O-carborane
DOI10.1016/j.ica.2003.05.001
Indexed BySCI
Language英语
WOS IDWOS:000188715300003
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:29[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82402
Collection中国科学院化学研究所
Corresponding AuthorJin, GX
Affiliation1.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Yu, XY,Lu, SX,Jin, GX,et al. Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands[J]. INORGANICA CHIMICA ACTA,2004,357(2):361-366.
APA Yu, XY,Lu, SX,Jin, GX,&Weng, LH.(2004).Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands.INORGANICA CHIMICA ACTA,357(2),361-366.
MLA Yu, XY,et al."Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands".INORGANICA CHIMICA ACTA 357.2(2004):361-366.
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