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A mini-TOF photofragment translational spectrometer - photofragmentation of CF3I at 281.73 nm
Tian, ZX; Bi, WB; Deng, HD; Wang, X; Tang, ZC; Zhu, QH
2004-12-11
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume400Issue:1-3Pages:15-18
AbstractUsing a very weak electric field to accelerate the photofragment ions, we have constructed a very simple photofragment translational spectrometer with only a 50 mm total flight path, but we can get photofragment translational spectra with high resolution. On this apparatus, we have performed the photodissociation of CF3I at 281.73 nm, and the same laser will ionize 1*((2)p(1/2)) via REMPI. Seven well-resolved vibrational peaks were obtained. Six of them are assigned to the umbrella vibrational mode v(2) = 0-5 states of photofragment CF3. The average internal energy E-int = 1928 cm(-1) is about 21% of the available energy. (C) 2004 Elsevier B.V. All rights reserved.
DOI10.1016/j.cplett.2004.10.071
Indexed BySCI
Language英语
WOS IDWOS:000225679200003
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82372
Collection中国科学院化学研究所
Corresponding AuthorZhu, QH
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Tian, ZX,Bi, WB,Deng, HD,et al. A mini-TOF photofragment translational spectrometer - photofragmentation of CF3I at 281.73 nm[J]. CHEMICAL PHYSICS LETTERS,2004,400(1-3):15-18.
APA Tian, ZX,Bi, WB,Deng, HD,Wang, X,Tang, ZC,&Zhu, QH.(2004).A mini-TOF photofragment translational spectrometer - photofragmentation of CF3I at 281.73 nm.CHEMICAL PHYSICS LETTERS,400(1-3),15-18.
MLA Tian, ZX,et al."A mini-TOF photofragment translational spectrometer - photofragmentation of CF3I at 281.73 nm".CHEMICAL PHYSICS LETTERS 400.1-3(2004):15-18.
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