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Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells
Wang, GQ; Zhou, XW; Li, MY; Zhang, JB; Kang, JJ; Lin, Y; Fang, SB; Xiao, XR
2004-11-02
Source PublicationMATERIALS RESEARCH BULLETIN
ISSN0025-5408
Volume39Issue:13Pages:2113-2118
AbstractGel polymer electrolytes were prepared by incorporating polyacrylonitrile (PAN) in a mixture of polysiloxane with quaternary ammonium side groups (PSQAS), ethylene carbonate (EC), propylene carbonate (PC) and iodine. The influence of PAN content on the ionic conductivity of gel polymer electrolytes and the charge-transfer kinetic performance in counterelectrode-electrolyte interface was investigated. The dye-sensitized solar cell with the gel polymer electrolyte containing 5 wt.% PAN showed the best photovoltaic performance; a maximum incident photon conversion efficiency of 63% at 520 nm was obtained, the short-circuit photocurrent density (J(sc)), the open- circuit voltage (V-oc) and the fill factor (FF) were 7 mA cm(-2), 0.565 V and 0.65, respectively. The corresponding overall conversion efficiency (eta) is 4.3%. (C) 2004 Elsevier Ltd. All rights reserved.
KeywordInterface Polymers Impedance Spectroscopy Ionic Conductivity
DOI10.1016/j.materresbull.2004.07.004
Indexed BySCI
Language英语
WOS IDWOS:000224535000015
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:51[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82368
Collection中国科学院化学研究所
Corresponding AuthorLin, Y
Affiliation1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Wang, GQ,Zhou, XW,Li, MY,et al. Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells[J]. MATERIALS RESEARCH BULLETIN,2004,39(13):2113-2118.
APA Wang, GQ.,Zhou, XW.,Li, MY.,Zhang, JB.,Kang, JJ.,...&Xiao, XR.(2004).Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells.MATERIALS RESEARCH BULLETIN,39(13),2113-2118.
MLA Wang, GQ,et al."Gel polymer electrolytes based on polyacrylonitrile and a novel quaternary ammonium salt for dye-sensitized solar cells".MATERIALS RESEARCH BULLETIN 39.13(2004):2113-2118.
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