ICCAS OpenIR
The influence of silicon-containing acrylate as active diluent on the properties of UV-cured epoxydiacrylate films
Liu, HB; Chen, MC; Huang, ZT; Xu, K; Zhang, XJ
2004-03-01
Source PublicationEUROPEAN POLYMER JOURNAL
ISSN0014-3057
Volume40Issue:3Pages:609-613
AbstractA new silicon-containing acrylate, which can be a good active diluent for UV-curable epoxydiacrylate systems, was prepared by reacting N-cyclohexyl-gamma-aminopropylmethyldimethoxysilane (CAMS) with trimethylolpropane triacrylate (TMPTA) by Michael-type addition reaction. The reactivity of -NH groups of CAMS with the acrylic groups of TMPTA was characterized by FTIR. The contents of the new active diluent in the UV-cured polymeric films were varied between 5% and 15% by weight. Mechanical, physical, and thermal characterizations of the UV-cured films were investigated: An increase in silicon-containing acrylate content caused a dramatic change of the surface properties of the films, and a decrease in mechanical properties besides the relative elongation. Thermogravimetric analysis of silicon-containing acrylate revealed that incorporating silicon into the structure resulted in a high char yield at 700 C. Water absorption values of UV-cured films were also affected by the amount of silicon-containing acrylate. (C) 2003 Elsevier Ltd. All rights reserved.
KeywordUv-curable Epoxydiacrylate Silicon Films Photopolymerization Diluent
DOI10.1016/j.eurpolymj.2003.10.018
Indexed BySCI
Language英语
WOS IDWOS:000189257100019
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82360
Collection中国科学院化学研究所
Corresponding AuthorLiu, HB
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Chem, Polymer Div 7, Guangzhou 510650, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Liu, HB,Chen, MC,Huang, ZT,et al. The influence of silicon-containing acrylate as active diluent on the properties of UV-cured epoxydiacrylate films[J]. EUROPEAN POLYMER JOURNAL,2004,40(3):609-613.
APA Liu, HB,Chen, MC,Huang, ZT,Xu, K,&Zhang, XJ.(2004).The influence of silicon-containing acrylate as active diluent on the properties of UV-cured epoxydiacrylate films.EUROPEAN POLYMER JOURNAL,40(3),609-613.
MLA Liu, HB,et al."The influence of silicon-containing acrylate as active diluent on the properties of UV-cured epoxydiacrylate films".EUROPEAN POLYMER JOURNAL 40.3(2004):609-613.
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