ICCAS OpenIR
Molecular rectangle formed by head-to-tail self-assembly of 1-(dipyrrin-2-yl)-1 '-(dipyrrin-3-yl)methane
Yang, L; Zhang, Y; Chen, Q; Ma, JS
2004-02-01
Source PublicationMONATSHEFTE FUR CHEMIE
ISSN0026-9247
Volume135Issue:2Pages:223-229
Abstract1-(Dipyrrin-2-yl)-1'-(dipyrrin-3-yl)methane, the N-confused analog of biladiene-ac, is prepared by condensation of 2,3'-dipyrromethane with two molecules of 2-formylpyrrole in dichloromethane in the presence of hydrogen bromide. Self-assembly of the ligand with Zn(II) in dichloromethane and methanol offers a dinuclear dimeric complex with a ligand:metal ratio of 2:2. X-Ray crystal structure analysis reveals two ligands bound through a head-to-tail pattern to two zinc centers to form a severely distorted helical conformation, which has the shape of a rectangle.
KeywordSelf-assembly Dipyrrin 1-(Dipyrrin-2-yl)-1 '-(Dipyrrin-3-yl) Methane Biladiene-ac Dinuclear Dimeric Complex
DOI10.1007/s00706-003-0099-9
Indexed BySCI ; IC
Language英语
WOS IDWOS:000188749700008
PublisherSPRINGER-VERLAG WIEN
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82354
Collection中国科学院化学研究所
Corresponding AuthorMa, JS
Affiliation1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China
2.BioMarin Pharmaceut Inc, Novato, CA 94949 USA
Recommended Citation
GB/T 7714
Yang, L,Zhang, Y,Chen, Q,et al. Molecular rectangle formed by head-to-tail self-assembly of 1-(dipyrrin-2-yl)-1 '-(dipyrrin-3-yl)methane[J]. MONATSHEFTE FUR CHEMIE,2004,135(2):223-229.
APA Yang, L,Zhang, Y,Chen, Q,&Ma, JS.(2004).Molecular rectangle formed by head-to-tail self-assembly of 1-(dipyrrin-2-yl)-1 '-(dipyrrin-3-yl)methane.MONATSHEFTE FUR CHEMIE,135(2),223-229.
MLA Yang, L,et al."Molecular rectangle formed by head-to-tail self-assembly of 1-(dipyrrin-2-yl)-1 '-(dipyrrin-3-yl)methane".MONATSHEFTE FUR CHEMIE 135.2(2004):223-229.
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