ICCAS OpenIR
Graft copolymerization of methyl methacrylate onto starch using potassium ditelluratocuprate(III)
Liu, YH; Li, JB; Yang, LY; Shi, ZQ; Deng, KL
2004-08-01
Source PublicationJOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
ISSN1060-1325
VolumeA41Issue:9Pages:1025-1035
AbstractThe graft copolymerization of methyl methacrylate (MMA) onto starch with potassium ditelluratocuprate(III) (DTC)-starch redox system as initiator was studied in alkaline medium. The grafting parameters have been determined as a function of temperature, ratio of monomer to starch, initiator concentration, and pH. The structure of the graft copolymers was confirmed by Fourier transform infrared spectroscopy (FTIR), x-ray diffraction, and scanning electron microscope (SEM). The thermal stability of starch and starch-g-PMMA were characterized by thermogravimetric analysis (TGA). It was found that the DTC-starch system is an efficient redox initiator for this graft copolymerization. A reaction mechanism is proposed to explain the formation of radicals and the initiation.
KeywordPotassium Diperiodatocuprate(Iii)[Dtc] Starch Starch-g-pmma Graft Copolymer
DOI10.1081/MA-200026135
Indexed BySCI
Language英语
WOS IDWOS:000224162500004
PublisherMARCEL DEKKER INC
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82304
Collection中国科学院化学研究所
Corresponding AuthorLiu, YH
Affiliation1.Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, YH,Li, JB,Yang, LY,et al. Graft copolymerization of methyl methacrylate onto starch using potassium ditelluratocuprate(III)[J]. JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY,2004,A41(9):1025-1035.
APA Liu, YH,Li, JB,Yang, LY,Shi, ZQ,&Deng, KL.(2004).Graft copolymerization of methyl methacrylate onto starch using potassium ditelluratocuprate(III).JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY,A41(9),1025-1035.
MLA Liu, YH,et al."Graft copolymerization of methyl methacrylate onto starch using potassium ditelluratocuprate(III)".JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY A41.9(2004):1025-1035.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, YH]'s Articles
[Li, JB]'s Articles
[Yang, LY]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, YH]'s Articles
[Li, JB]'s Articles
[Yang, LY]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, YH]'s Articles
[Li, JB]'s Articles
[Yang, LY]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.