ICCAS OpenIR
A study on the phase behavior of the system CO2+CO+H-2+1-hexene plus heptanal
Jiang, T; Hou, ZS; Han, BX; Gao, L; Liu, ZM; He, J; Yang, GY
2004-01-15
Source PublicationFLUID PHASE EQUILIBRIA
ISSN0378-3812
Volume215Issue:1Pages:85-89
AbstractThe phase behavior of a system of importance for the hydroformylation reaction of 1-hexene in supercritical CO2 has been studied in the range of 303.2-348.2 K with different CO2 mole fractions. The conversion of 1-hexene varies from 0 to 1. The density of the reaction mixture at different conditions are also determined. It is demonstrated that the phase behavior changes with conversion of 1-hexene. At zero conversion, the phase separation pressure increases with increasing concentration of the reactants in the reaction system and decreases slightly with the increase of temperature. At other conversions, the phase separation pressure increases as temperature rises. The density of the reaction mixture at phase separation point is higher at the larger conversions. (C) 2003 Elsevier B.V. All rights reserved.
KeywordSupercritical Co2 Phase Behavior 1-hexene Hydroformylation
DOI10.1016/S0378-3812(03)00366-2
Indexed BySCI
Language英语
WOS IDWOS:000188646300011
PublisherELSEVIER SCIENCE BV
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82276
Collection中国科学院化学研究所
Corresponding AuthorHan, BX
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Jiang, T,Hou, ZS,Han, BX,et al. A study on the phase behavior of the system CO2+CO+H-2+1-hexene plus heptanal[J]. FLUID PHASE EQUILIBRIA,2004,215(1):85-89.
APA Jiang, T.,Hou, ZS.,Han, BX.,Gao, L.,Liu, ZM.,...&Yang, GY.(2004).A study on the phase behavior of the system CO2+CO+H-2+1-hexene plus heptanal.FLUID PHASE EQUILIBRIA,215(1),85-89.
MLA Jiang, T,et al."A study on the phase behavior of the system CO2+CO+H-2+1-hexene plus heptanal".FLUID PHASE EQUILIBRIA 215.1(2004):85-89.
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