ICCAS OpenIR
A novel heterospin tetranuclear (MnCu3II)-Cu-II-type complex incorporating a macrocyclic oxamide [Mn(CuL)(3)](ClO4)(2): Synthesis, crystal structure and magnetic properties
Liu, ZL; Zhang, DQ; Luo, JL; Jiang, ZH; Liao, DZ; Zhu, DB
2004-05-20
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume57Issue:8Pages:647-655
AbstractA novel oxamidato-bridged (MnCu3II)-Cu-II heterospin tetranuclear complex incorporating a macrocyclic oxamide, 2,3-dioxo-5,6:14,15-dibenzo-1,4,8,12-tetraazacyclopentadeca-7,12-diene, was prepared and characterized spectroscopically, structurally and magnetically. The structure consists of tetranuclear units in which the central manganese(II) atom is linked to each external copper(II) ion via the exo-cis oxygen atoms of the oxamidato macrocyclic ligand. The temperature dependence of the magnetic susceptibility for the complex was analyzed by means of the Hamiltonian H = -2JS(Mn)(S-Cu1 + S-Cu2 + S-Cu3) with J = -14.01 cm(-1).
KeywordMacrocyclic Oxamide Heterospin Complex Crystal Structure Spectroscopic Characterization Magnetic Property
DOI10.1080/00958970410001704573
Indexed BySCI
Language英语
WOS IDWOS:000222897300004
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82196
Collection中国科学院化学研究所
Corresponding AuthorZhang, DQ
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
3.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
Recommended Citation
GB/T 7714
Liu, ZL,Zhang, DQ,Luo, JL,et al. A novel heterospin tetranuclear (MnCu3II)-Cu-II-type complex incorporating a macrocyclic oxamide [Mn(CuL)(3)](ClO4)(2): Synthesis, crystal structure and magnetic properties[J]. JOURNAL OF COORDINATION CHEMISTRY,2004,57(8):647-655.
APA Liu, ZL,Zhang, DQ,Luo, JL,Jiang, ZH,Liao, DZ,&Zhu, DB.(2004).A novel heterospin tetranuclear (MnCu3II)-Cu-II-type complex incorporating a macrocyclic oxamide [Mn(CuL)(3)](ClO4)(2): Synthesis, crystal structure and magnetic properties.JOURNAL OF COORDINATION CHEMISTRY,57(8),647-655.
MLA Liu, ZL,et al."A novel heterospin tetranuclear (MnCu3II)-Cu-II-type complex incorporating a macrocyclic oxamide [Mn(CuL)(3)](ClO4)(2): Synthesis, crystal structure and magnetic properties".JOURNAL OF COORDINATION CHEMISTRY 57.8(2004):647-655.
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