ICCAS OpenIR
Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate
Li, Q; Wu, PF; Wei, YG; Wang, Y; Wang, P; Guo, HY
2004-04-01
Source PublicationINORGANIC CHEMISTRY COMMUNICATIONS
ISSN1387-7003
Volume7Issue:4Pages:524-527
AbstractA novel bifunctionalized arylimido derivative of hexamolybdate, (Bu4N)(2)[Mo6O17(dropNAr)(2)](2-) (Ar = o-CH3C6H4) 1, in which the two o-tolylimido groups are bounded to hexamolybdate at the cis positions, was synthesized by self-assembled metathesis of alpha-type octamolybdate ion and o-toluidine with DCC as a dehydration agent. The most interesting characteristic of 1 is that the cluster anions form dimers via the pi-pi stacking between one of its two phenyl rings, and four such dimers are linked in turn via C-H... O hydrogen bonding involving terminal hexamolybdate oxygen atoms into ring-like tetramers in the solid state. (C) 2004 Elsevier B.V. All rights reserved.
KeywordPolyoxometalates Organoimido Derivatives Dcc Supramolecular Assembly Crystal Structure
DOI10.1016/j.inoche.2004.01.016
Indexed BySCI
Language英语
WOS IDWOS:000220553200018
PublisherELSEVIER SCIENCE BV
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82176
Collection中国科学院化学研究所
Corresponding AuthorWei, YG
Affiliation1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Dept Chem, Beijing 100871, Peoples R China
2.Beijing Univ Chem Technol, Dept Chem, Beijing 100029, Peoples R China
3.Hubei Polytech Univ, Dept Bioengn, Wuhan 430068, Peoples R China
Recommended Citation
GB/T 7714
Li, Q,Wu, PF,Wei, YG,et al. Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2004,7(4):524-527.
APA Li, Q,Wu, PF,Wei, YG,Wang, Y,Wang, P,&Guo, HY.(2004).Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate.INORGANIC CHEMISTRY COMMUNICATIONS,7(4),524-527.
MLA Li, Q,et al."Synthesis, structure and supramolecular assembly in the crystalline state of a bifunctionalized arylimido derivative of hexamolybdate".INORGANIC CHEMISTRY COMMUNICATIONS 7.4(2004):524-527.
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