ICCAS OpenIR
Adsorption and coordination of tartaric acid enantiomers on Cu(111) in aqueous solution
Yan, HJ; Wang, D; Han, MJ; Wan, LJ; Bai, CL
2004-08-31
Source PublicationLANGMUIR
ISSN0743-7463
Volume20Issue:18Pages:7360-7364
AbstractChiral modifiers have gained much attention because they can induce high enantioselectivity on reactive metal surface in heterogeneous enantioselective catalysis. The high enantioselectivity is attributed to that the chirality of modifiers is bestowed onto the metal surface upon adsorption. Much study on the adsorption of modifiers on metal surface has been performed in an ultrahigh vacuum. In this paper, the adsorption of tartaric acid on Cu(111) has been studied by electrochemical scanning tunneling microscopy (STM) in aqueous solution. It is found that (R,R)-tartaric acid and (S,S)-tartaric acid can form a well-ordered adlayer on the Cu(111) surface with a (4 x 4) symmetry. A dimeric structure is proposed in the temporary model from STM observation.
DOI10.1021/la035283y
Indexed BySCI
Language英语
WOS IDWOS:000223567900004
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82132
Collection中国科学院化学研究所
Corresponding AuthorWan, LJ
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Yan, HJ,Wang, D,Han, MJ,et al. Adsorption and coordination of tartaric acid enantiomers on Cu(111) in aqueous solution[J]. LANGMUIR,2004,20(18):7360-7364.
APA Yan, HJ,Wang, D,Han, MJ,Wan, LJ,&Bai, CL.(2004).Adsorption and coordination of tartaric acid enantiomers on Cu(111) in aqueous solution.LANGMUIR,20(18),7360-7364.
MLA Yan, HJ,et al."Adsorption and coordination of tartaric acid enantiomers on Cu(111) in aqueous solution".LANGMUIR 20.18(2004):7360-7364.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yan, HJ]'s Articles
[Wang, D]'s Articles
[Han, MJ]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yan, HJ]'s Articles
[Wang, D]'s Articles
[Han, MJ]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yan, HJ]'s Articles
[Wang, D]'s Articles
[Han, MJ]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.