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Synthesis and crystal structure of an inorganic-organic hybrid [DMAPM](+)[CdI3](-): The first example of Cd2I62- dimer
Ren, P; Qin, JG; Zhang, DQ; Hu, HM
2004
Source PublicationCHINESE JOURNAL OF STRUCTURAL CHEMISTRY
ISSN0254-5861
Volume23Issue:7Pages:735-738
AbstractA new inorganic-organic hybrid, [DMAPM](+)[CdI3](-) (DMAPM(+) = p-dimethylamino-1- methyl-pyridinium), has been synthesized by the reaction of [DMAPM](+)Gamma and CdI2, and characterized by IR and elemental analysis. The crystal structure was obtained via X-ray single-crystal diffraction with the following data: triclinic, space group P (1) over bar, a = 8.0974(9), b = 9.6187(10), c = 10.5028(8) Angstrom, alpha = 75.049(6), beta = 86.321(3), gamma = 87.791(3)degrees, V = 788.50(13) Angstrom(3), D-c = 2.655 g/cm(3), Z = 2, R = 0.0385 and wR = 0.0976. In the structure, one cadmium and four iodine atoms form a tetrahedral geometry, and two of such tetrahedra are connected in a co-line way to constitute Cd2I62- dimer. To our knowledge, this is the first example of dimerized CdI4 tetrahedron. All of the dimers are packed in the same mode, while the [DMAPM](+) cations are anti-parallelly arrayed.
KeywordHybrid Synthesis Crystal Structure Dimer
Indexed BySCI
Language英语
WOS IDWOS:000223488600004
PublisherCHINESE JOURNAL STRUCTURAL CHEMISTRY
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82100
Collection中国科学院化学研究所
Corresponding AuthorQin, JG
Affiliation1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Ren, P,Qin, JG,Zhang, DQ,et al. Synthesis and crystal structure of an inorganic-organic hybrid [DMAPM](+)[CdI3](-): The first example of Cd2I62- dimer[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2004,23(7):735-738.
APA Ren, P,Qin, JG,Zhang, DQ,&Hu, HM.(2004).Synthesis and crystal structure of an inorganic-organic hybrid [DMAPM](+)[CdI3](-): The first example of Cd2I62- dimer.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,23(7),735-738.
MLA Ren, P,et al."Synthesis and crystal structure of an inorganic-organic hybrid [DMAPM](+)[CdI3](-): The first example of Cd2I62- dimer".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 23.7(2004):735-738.
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