ICCAS OpenIR
Second-sphere coordination of the tris(5,5 '-diamino-2,2 '-bipyridine)iron complex with arene-carboxylate ligands through N-H center dot center dot center dot O hydrogen bonding
Yang, XJ; Wu, B; Janiak, C; Sun, WH; Hu, HM
2004
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN0044-2313
Volume630Issue:11Pages:1564-1572
AbstractThe tris(5,5'-diamino-2,2'-bipyridine)iron(II) complex [Fe(DABP)(3)](2+) can be engaged in hydrogen-bonding interactions from the amino groups to carboxylate-containing molecules as H-bond acceptors. This so-called second-sphere coordination of the metal complex is investigated here by using benzene-1,4-dicarboxylate (terephthalate, L-1), benzene-1,3-dicarboxylate (isophthalate, L-2), biphenyt-2,2'-dicarboxylate (L-3), and benzene-1,3,5-tricarboxylate (trimesate, L-4) anions for N-(HO)-O-... bonding. The second-sphere coordination of [Fe(DABP)(3)](2+) is further complemented by water molecules of crystallization in the isolated and structurally elucidated compounds of [Fe(DABP)(3)](L-1)(.)5H(2)O, [Fe(DABP)(3)](L-2)(.)8H(2)O, [Fe(DABP)(3)](L-1)(.)5H(2)O, and [Fe(DABP)(3)](3)(L-4)(2)(.)20H(2)O. The hydrogen-bonding between [Fe(DABP)(3)](2+) and the dicarboxylate anions (L-1-L-3) decreases from a three-dimensional supramolecular network (with V) to discrete units (with L 2 and V) with the increasing number of crystal water molecules. The tricarboxylate ligand L-4 is capable of capping the triangular face formed by the three amino groups in [Fe(DABP)(3)](2+). The solid-state structures of DABP(.)2H(2)O and 5,5'-bis(ethoxycarbonylamino)-2,2'-bipyridine (BEBP) are reported.
KeywordSecond-sphere Coordination Supramolecular Chemistry Hydrogen Bonding Bipyridine Complexes Iron Complex
DOI10.1002/zaac.200400175
Indexed BySCI
Language英语
WOS IDWOS:000224247600010
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82092
Collection中国科学院化学研究所
Corresponding AuthorJaniak, C
Affiliation1.Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany
2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Yang, XJ,Wu, B,Janiak, C,et al. Second-sphere coordination of the tris(5,5 '-diamino-2,2 '-bipyridine)iron complex with arene-carboxylate ligands through N-H center dot center dot center dot O hydrogen bonding[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2004,630(11):1564-1572.
APA Yang, XJ,Wu, B,Janiak, C,Sun, WH,&Hu, HM.(2004).Second-sphere coordination of the tris(5,5 '-diamino-2,2 '-bipyridine)iron complex with arene-carboxylate ligands through N-H center dot center dot center dot O hydrogen bonding.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,630(11),1564-1572.
MLA Yang, XJ,et al."Second-sphere coordination of the tris(5,5 '-diamino-2,2 '-bipyridine)iron complex with arene-carboxylate ligands through N-H center dot center dot center dot O hydrogen bonding".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 630.11(2004):1564-1572.
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