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A novel coordination polymer, [Ag-4(I)(bpdc)(H(2)bpdc)(Hbpdc)(2)]n(bpdc=2,2'-bipyridyl-3,3'-dicarboxylate): Coordination models of bpdc ligands
Guo, HY; Chen, CX; Wei, YG; Jin, XL; Fang, C; Wang, P
2004-08-01
Source PublicationCHINESE JOURNAL OF CHEMISTRY
ISSN1001-604X
Volume22Issue:8Pages:816-821
AbstractA novel coordination polymer, [Ag-4(bpdc)(H(2)bpdc)(Hbpdc)(2)](n) (bpdc=2,2'-bipyridyl-3,3'-dicarboxylate), was hydrothermally synthesized at 403 K and structurally characterized by single crystal X-ray diffraction analysis. The compound crystalizes in the monoclinic space group C2/c with a= 1.9516(4) rim, b=1.9503(4) nm, c=1.2566(3) nm, and beta= 112.48(3)degrees. In the two-dimensional crystal structure, Ag-I center is coordinated, in a scarce coordination environment, double-capped tetrahedron, by one bpdc ligand to form N-Ag-N chelate bond via two pyridyl N atoms, and other two bpdc ligands to form two O-Ag-O chelate bonds, respectively, via two carboxyl 0 atoms. The bpdc ligands are present in one non-protonated form, bpdc, and two protonated forms, Hbpdc and H2bpdc, which all act as mu(3)-ligand in a hexadentate fashion (N, N'; 0, O'; 0, O') to coordinate with three Ag centers, respectively, through the three chelate bonds. This coordinated fashion of bpdc ligand is first found in the title compound. UV-Vis-NIR reflectance spectroscopy study revealed insulator nature for the crystal with an optical energy gap of 3.1 eV.
KeywordCoordination Polymer Silver Crystal Structure 2 2'-bipyridyl-3 3'-dicarboxylate
Indexed BySCI
Language英语
WOS IDWOS:000223452500009
PublisherSCIENCE CHINA PRESS
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/82084
Collection中国科学院化学研究所
Corresponding AuthorGuo, HY
Affiliation1.Beijing Univ Chem Technol, Dept Chem, Beijing 100029, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
Recommended Citation
GB/T 7714
Guo, HY,Chen, CX,Wei, YG,et al. A novel coordination polymer, [Ag-4(I)(bpdc)(H(2)bpdc)(Hbpdc)(2)]n(bpdc=2,2'-bipyridyl-3,3'-dicarboxylate): Coordination models of bpdc ligands[J]. CHINESE JOURNAL OF CHEMISTRY,2004,22(8):816-821.
APA Guo, HY,Chen, CX,Wei, YG,Jin, XL,Fang, C,&Wang, P.(2004).A novel coordination polymer, [Ag-4(I)(bpdc)(H(2)bpdc)(Hbpdc)(2)]n(bpdc=2,2'-bipyridyl-3,3'-dicarboxylate): Coordination models of bpdc ligands.CHINESE JOURNAL OF CHEMISTRY,22(8),816-821.
MLA Guo, HY,et al."A novel coordination polymer, [Ag-4(I)(bpdc)(H(2)bpdc)(Hbpdc)(2)]n(bpdc=2,2'-bipyridyl-3,3'-dicarboxylate): Coordination models of bpdc ligands".CHINESE JOURNAL OF CHEMISTRY 22.8(2004):816-821.
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