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Novel chiral dendritic diphosphine ligands for Rh(I)-catalyzed asymmetric hydrogenation: Remarkable structural effects on catalytic properties
Yi, B; Fan, QH; Deng, GJ; Li, YM; Qiu, LQ; Chan, ASC
2004-04-29
Source PublicationORGANIC LETTERS
ISSN1523-7060
Volume6Issue:9Pages:1361-1364
AbstractA series of dendritic ligands with a chiral diphosphine located at the focal point have been synthesized through coupling of pyrphos 2 with Frechet-type polyether dendron 3. The relationship between the primary structure of the dendrimer and its catalytic properties was established in the Rh-catalyzed asymmetric hydrogenation of alpha-acetamido cinnamic acid 4. A remarkable structural effect on catalytic activity was observed.
DOI10.1021/ol036512a
Indexed BySCI ; IC ; CCR
Language英语
WOS IDWOS:000221038000006
PublisherAMER CHEMICAL SOC
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81888
Collection中国科学院化学研究所
Corresponding AuthorYi, B
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Biol Chem Lab, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai, Peoples R China
3.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
Recommended Citation
GB/T 7714
Yi, B,Fan, QH,Deng, GJ,et al. Novel chiral dendritic diphosphine ligands for Rh(I)-catalyzed asymmetric hydrogenation: Remarkable structural effects on catalytic properties[J]. ORGANIC LETTERS,2004,6(9):1361-1364.
APA Yi, B,Fan, QH,Deng, GJ,Li, YM,Qiu, LQ,&Chan, ASC.(2004).Novel chiral dendritic diphosphine ligands for Rh(I)-catalyzed asymmetric hydrogenation: Remarkable structural effects on catalytic properties.ORGANIC LETTERS,6(9),1361-1364.
MLA Yi, B,et al."Novel chiral dendritic diphosphine ligands for Rh(I)-catalyzed asymmetric hydrogenation: Remarkable structural effects on catalytic properties".ORGANIC LETTERS 6.9(2004):1361-1364.
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