ICCAS OpenIR
Synthesis and structure of a dipyrazol-bridged macrocyclic palladium(II) complex
Zhang, ZX; Huang, H; Yu, SY
2004-07-01
Source PublicationCHINESE JOURNAL OF INORGANIC CHEMISTRY
ISSN1001-4861
Volume20Issue:7Pages:849-852
AbstractA dipyrazol-bridged macrocyclic palladium(II) complex [(Pd(en))(4)L-4](NO3)(8) (en=ethylenediamine, L=3,3',5,5'-tetramethyldipyrazol) 1 was prepared in water through a [4+4] macrocyclization of cis-(ethylenediamine)Pd(II) nitrate and the neutral form of the dipyrazol ligand 3,3' 5,5'-tetramethyldipyrazol. This cationic palladium macrocycle is highly distorted rather than a planar macrocycle and can hold eight nitrate anions around the macrocyclic framework through both hydrogen bonding and electrostatic interactions.
KeywordDipyrazol-bridged Palladium(Ii) Complex Hydrogen Bond Crystal Structure
Indexed BySCI
Language英语
WOS IDWOS:000222365000018
PublisherCHINESE CHEMICAL SOCIETY
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81812
Collection中国科学院化学研究所
Corresponding AuthorZhang, ZX
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, ZX,Huang, H,Yu, SY. Synthesis and structure of a dipyrazol-bridged macrocyclic palladium(II) complex[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2004,20(7):849-852.
APA Zhang, ZX,Huang, H,&Yu, SY.(2004).Synthesis and structure of a dipyrazol-bridged macrocyclic palladium(II) complex.CHINESE JOURNAL OF INORGANIC CHEMISTRY,20(7),849-852.
MLA Zhang, ZX,et al."Synthesis and structure of a dipyrazol-bridged macrocyclic palladium(II) complex".CHINESE JOURNAL OF INORGANIC CHEMISTRY 20.7(2004):849-852.
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