ICCAS OpenIR
Reaction of AgN3 with SOCl2: Evidence for the formation of thionyl azide, SO(N-3)(2)
Zeng, XQ; Liu, FY; Qiao, S; Ge, MF; Zhang, JP; Ai, XC; Meng, LP; Zheng, SJ; Wang, DX
2004-08-09
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume43Issue:16Pages:4799-4801
AbstractPure thionyl azide SO(N-3)(2), which is the only gaseous reaction product, has been generated in a vacuum by the heterogeneous reaction of SOCl2 vapor with AgN3 at room temperature at a SOCl2 vapor pressure of 1 x 10(-3) Torr. Evidence for the formation of SO(N-3)(2) is given by on line photoelectron spectroscopy (PES) combined with outer valence Green's function (OVGF) calculations with the 6-311++G(2df) basis set. The good agreement between the PES experiment and the OVGF calculation shows that SO(N-3)(2) has C-1 symmetry. The first ionization energy of SO(N-3)(2) is 10.18 eV.
DOI10.1021/ic049442s
Indexed BySCI
Language英语
WOS IDWOS:000223190300009
PublisherAMER CHEMICAL SOC
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81756
Collection中国科学院化学研究所
Corresponding AuthorWang, DX
Affiliation1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China
2.Hebei Normal Univ, Open Lab Computat Quantum Chem, Shijiazhuang 050091, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Zeng, XQ,Liu, FY,Qiao, S,et al. Reaction of AgN3 with SOCl2: Evidence for the formation of thionyl azide, SO(N-3)(2)[J]. INORGANIC CHEMISTRY,2004,43(16):4799-4801.
APA Zeng, XQ.,Liu, FY.,Qiao, S.,Ge, MF.,Zhang, JP.,...&Wang, DX.(2004).Reaction of AgN3 with SOCl2: Evidence for the formation of thionyl azide, SO(N-3)(2).INORGANIC CHEMISTRY,43(16),4799-4801.
MLA Zeng, XQ,et al."Reaction of AgN3 with SOCl2: Evidence for the formation of thionyl azide, SO(N-3)(2)".INORGANIC CHEMISTRY 43.16(2004):4799-4801.
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