ICCAS OpenIR
Catalytic behavior of wool-osmium tetroxide complex for asymmetric dihydroxylation of olefins
Miao, JH; Yang, JH; Chen, LY; Tu, BX; Huang, MY; Jiang, YY
2004-04-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume15Issue:4Pages:221-224
AbstractA new chiral polymer-metal complex, wool-osmium tetroxide (wool-OsO4) complex was prepared by a very simple method. This complex was found to be able to catalyze the asymmetric dihydroxylation of allylamine to (R)-(+)-3-amino-1,2-propanediol and allyl chloride to (S)-(+)-3-chloro-1,2-propanediol. The optical yields amounted to 83.7 and 57.2%, and the product yields were 80.2 and 68.5% respectively. The experimental results showed that OsO4 content in the complex, reaction time, allylamine/OsO4 molar ratio and solvent all have an effect on the product and optical yields. Additionally, wool-OsO4 complex catalyst could be reused without any remarkable change in optical catalytic activity. Copyright (C) 2004 John Wiley Sons, Ltd.
KeywordWool-osmium Tetroxide Asymmetric Dihydroxylation Allylamine Allyl Chloride
DOI10.1002/pat.439
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000220839900011
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81692
Collection中国科学院化学研究所
Corresponding AuthorMiao, JH
Affiliation1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Peoples R China
Recommended Citation
GB/T 7714
Miao, JH,Yang, JH,Chen, LY,et al. Catalytic behavior of wool-osmium tetroxide complex for asymmetric dihydroxylation of olefins[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2004,15(4):221-224.
APA Miao, JH,Yang, JH,Chen, LY,Tu, BX,Huang, MY,&Jiang, YY.(2004).Catalytic behavior of wool-osmium tetroxide complex for asymmetric dihydroxylation of olefins.POLYMERS FOR ADVANCED TECHNOLOGIES,15(4),221-224.
MLA Miao, JH,et al."Catalytic behavior of wool-osmium tetroxide complex for asymmetric dihydroxylation of olefins".POLYMERS FOR ADVANCED TECHNOLOGIES 15.4(2004):221-224.
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