ICCAS OpenIR
Asymmetric hydrogenation of ketones catalyzed by silica-supported chitosan-iron-nickel complex
Zhou, DQ; Zhou, DJ; Cui, XH; Wang, FM; Huang, MY; Jiang, YY
2004-06-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume15Issue:6Pages:350-354
AbstractA new silica-supported biopolymer-metal complex, silica-supported chitosan-iron-nickel complex was prepared by a very simple method. This complex catalyst can be used as a catalyst in the asymmetric hydrogenation of propiophenone to (R)-(+)-1-phenyl-1-propanol and acetophenone to (R)(+)-1-phenyl ethanol in 91.7 and 77.7% optical yields, respectively, at 110 C and under 70 kg/cm(2) pressure. The catalyst could be reused several times without any remarkable change in the catalytic activity. Copyright (C) 2004 John Wiley Sons, Ltd.
KeywordAsymmetric Hydrogenation Silica-supported Chitosar-iron-nickel Catalyst Propiophenone Acetophenone 1-phenyl-1propanol 1-phenyl Ethanol
DOI10.1002/pat.442
Indexed BySCI
Language英语
WOS IDWOS:000221802200011
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81662
Collection中国科学院化学研究所
Corresponding AuthorZhou, DJ
AffiliationChinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhou, DQ,Zhou, DJ,Cui, XH,et al. Asymmetric hydrogenation of ketones catalyzed by silica-supported chitosan-iron-nickel complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2004,15(6):350-354.
APA Zhou, DQ,Zhou, DJ,Cui, XH,Wang, FM,Huang, MY,&Jiang, YY.(2004).Asymmetric hydrogenation of ketones catalyzed by silica-supported chitosan-iron-nickel complex.POLYMERS FOR ADVANCED TECHNOLOGIES,15(6),350-354.
MLA Zhou, DQ,et al."Asymmetric hydrogenation of ketones catalyzed by silica-supported chitosan-iron-nickel complex".POLYMERS FOR ADVANCED TECHNOLOGIES 15.6(2004):350-354.
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