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In situ copolymerization of ethylene to produce linear low-density polyethylene by Ti(OBu)(4)/AlEt3-MAO/SiO2/Et(Ind)(2)ZrCl2
Zhu, BC; Guo, CY; Liu, ZY; Yin, YQ
2004-12-15
Source PublicationJOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995
Volume94Issue:6Pages:2451-2455
AbstractLinear low-density polyethylene (LLDPE) is produced in a reactor from single ethylene feed by combining Ti(OBu)(4)/AlEt3, capable of forming alpha-olefins (predominantly 1-butene), with SiO2-supported Et(Ind)(2)ZrCl2 (denoted MAO/SiO2/Et(lnd)(2)ZrCl2), which is able to copolymerize ethylene and 1-butene in situ with little interference in the dual-functional catalytic system. The two catalysts in the dual-functional catalytic system match well because of the employment of triethylaluminum (AlEt3) as the single cocatalyst to both Ti(OBu)(4) and MAO/SiO2/Et(Ind)(2)ZrCl2, exhibiting high polymerization activity and improved properties of the obtained polyethylene. There is a noticeable increment in catalytic activity when the amount of Ti(OBU)(4) in the reactor increases and I-butene can be incorporated by about 6.51 mol % in the backbone of polyethylene chains at the highest Ti(OBU)(4) concentration in the feed. The molecular weights (M-w), melting points, and crystallinity of the LLDPE descend as the amount of Ti(OBU)(4) decreases, which is attributed mainly to chain termination and high branching degree, while the molecular weight distribution remains within a narrow range as in the case of metallocene catalysts. (C) 2004 Wiley Periodicals, Inc.
KeywordCopolymerization Polyethylene Linear
DOI10.1002/app.21190
Indexed BySCI
Language英语
WOS IDWOS:000224925000028
PublisherJOHN WILEY & SONS INC
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81644
Collection中国科学院化学研究所
Corresponding AuthorGuo, CY
Affiliation1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, CAS Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Zhu, BC,Guo, CY,Liu, ZY,et al. In situ copolymerization of ethylene to produce linear low-density polyethylene by Ti(OBu)(4)/AlEt3-MAO/SiO2/Et(Ind)(2)ZrCl2[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2004,94(6):2451-2455.
APA Zhu, BC,Guo, CY,Liu, ZY,&Yin, YQ.(2004).In situ copolymerization of ethylene to produce linear low-density polyethylene by Ti(OBu)(4)/AlEt3-MAO/SiO2/Et(Ind)(2)ZrCl2.JOURNAL OF APPLIED POLYMER SCIENCE,94(6),2451-2455.
MLA Zhu, BC,et al."In situ copolymerization of ethylene to produce linear low-density polyethylene by Ti(OBu)(4)/AlEt3-MAO/SiO2/Et(Ind)(2)ZrCl2".JOURNAL OF APPLIED POLYMER SCIENCE 94.6(2004):2451-2455.
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