ICCAS OpenIR
The reaction of formyl radical with chlorine atom
Qu, ZW; Dong, F; Zhang, QY; Kong, FN
2004-03-11
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume386Issue:4-6Pages:384-389
AbstractThe radical-radical reaction of formyl radical with chlorine atom has been investigated by the time-resolved infrared emission spectroscopy and by the theoretical calculations at the UB3LYP/6-31++G(d,p) and single-point UCCSD(T)/6-311++G(d,p) levels. The products have been verified as the vibrationally excited CO (upsilonless than or equal to4) and HCl. The reaction is initiated by radical-radical recombination forming an intermediate of formaldehyde chloride, which further dissociates into the products of HCl and CO. (C) 2004 Elsevier B.V. All rights reserved.
DOI10.1016/j.cplett.2004.01.051
Indexed BySCI
Language英语
WOS IDWOS:000220124700030
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81584
Collection中国科学院化学研究所
Corresponding AuthorKong, FN
AffiliationChinese Acad Sci, Inst Chem, Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Qu, ZW,Dong, F,Zhang, QY,et al. The reaction of formyl radical with chlorine atom[J]. CHEMICAL PHYSICS LETTERS,2004,386(4-6):384-389.
APA Qu, ZW,Dong, F,Zhang, QY,&Kong, FN.(2004).The reaction of formyl radical with chlorine atom.CHEMICAL PHYSICS LETTERS,386(4-6),384-389.
MLA Qu, ZW,et al."The reaction of formyl radical with chlorine atom".CHEMICAL PHYSICS LETTERS 386.4-6(2004):384-389.
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