ICCAS OpenIR
The binary anion clusters of Ge/Sn, Ge/Pb, Sn/Pb, Co/Ge, Co/Sn and Co/Pb
Zhang, X; Tang, ZC; Gao, Z
2003
Source PublicationACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
Volume19Issue:1Pages:4-8
AbstractThe binary cluster anions of Ge/Sn, Ge/Pb, Sn/Pb, Co/Ge, Co/Sn and Co/Pb binary cluster ions, produced by direct laser ablation, were studied with a Tandem TOF mass spectrometer. The experiments show that E-1/E-2. (E-1/E-2 denotes Ge/Sn, Ge/Pb and Sn/Pb) binary clusters dominantly distribute in the lower mass region, in which the number of heavy atom is much larger than that of light atom. And composition and distribution of these binary clusters indicate that their structures and properties are similar to those pure group-14 elements cluster. By laser ablating the mixtures of transition metal cobalt and group-14 elements, mass spectra showed that abundance Co/E(E denotes Ge, Sn and Pb) cluster formed in higher mass range. Magic number CoGel(10)(-), CoSn10- and CoPb10- may have bi-capped tetragonal antiprism structure and CoPb12- is icosahedral structure. The difference between E-1/E-2 and Co/E binary cluster anions shows that all atoms for E-1/E-2 binary cluster anions are on the framework of the cage, while the cobalt atom for Co/E binary cluster is inside the cage of E.
KeywordLaser Ablation Binary Alloy Cluster Group-14 Elements Cage Structure
DOI10.3866/PKU.WHXB20030102
Indexed BySCI
Language英语
WOS IDWOS:000180539200002
PublisherPEKING UNIV PRESS
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81518
Collection中国科学院化学研究所
Corresponding AuthorTang, ZC
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, X,Tang, ZC,Gao, Z. The binary anion clusters of Ge/Sn, Ge/Pb, Sn/Pb, Co/Ge, Co/Sn and Co/Pb[J]. ACTA PHYSICO-CHIMICA SINICA,2003,19(1):4-8.
APA Zhang, X,Tang, ZC,&Gao, Z.(2003).The binary anion clusters of Ge/Sn, Ge/Pb, Sn/Pb, Co/Ge, Co/Sn and Co/Pb.ACTA PHYSICO-CHIMICA SINICA,19(1),4-8.
MLA Zhang, X,et al."The binary anion clusters of Ge/Sn, Ge/Pb, Sn/Pb, Co/Ge, Co/Sn and Co/Pb".ACTA PHYSICO-CHIMICA SINICA 19.1(2003):4-8.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhang, X]'s Articles
[Tang, ZC]'s Articles
[Gao, Z]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhang, X]'s Articles
[Tang, ZC]'s Articles
[Gao, Z]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhang, X]'s Articles
[Tang, ZC]'s Articles
[Gao, Z]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.