ICCAS OpenIR
Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)(2)}(2)(mu-S)(2)] building blocks
Zhang, WJ; Wu, XT; Wu, B; Yu, SY; Santoni, G; Rehder, D
2003-02-24
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume42Issue:4Pages:1130-1134
AbstractThe dimeric W-V complex [Et4N](4)[syn-{O=W(NCS)(3)}(2)(mu-S)(2)], 1, prepared from [Et4N](2)[WS4], SCN-, and Cd2+, shows interesting reactivity patterns in that the thiocyanate trans to the oxc, group can in part be replaced, initiated by Mn2+, by dimethylformamide (DMF) to form [Et4N](2.5)[{O=W(NCS)(2.25)(DMF)(1.25)}(2)(mu-S)(2)], 2. With Ag+, 1 undergoes partial replacement of SCN- by DMF and coordinates to the silver ions to generate {[Et4N](2.5)[{W2O2(NCS)(2)(mu-S)(2)}(mu-NCS)(2)(DMF){Ag-0.5(SCN)}]}(n), 3. Compound 3 constitutes a polymeric double-stranded chain, with normal bonding interactions [via W-(mu-NCS)-Ag] between the two strands, and moderate intrastrand [W-(mu-NCS)Ag-...] bonding. The crystal and molecular structures of the three compounds are described.
DOI10.1021/ic020510p
Indexed BySCI
Language英语
WOS IDWOS:000181116200032
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81436
Collection中国科学院化学研究所
Corresponding AuthorRehder, D
Affiliation1.Univ Hamburg, Inst Inorgan & Appl Chem, D-20146 Hamburg, Germany
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.Chinese Acad Sci, Fujian Inst Res & Struct Matter, Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
Recommended Citation
GB/T 7714
Zhang, WJ,Wu, XT,Wu, B,et al. Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)(2)}(2)(mu-S)(2)] building blocks[J]. INORGANIC CHEMISTRY,2003,42(4):1130-1134.
APA Zhang, WJ,Wu, XT,Wu, B,Yu, SY,Santoni, G,&Rehder, D.(2003).Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)(2)}(2)(mu-S)(2)] building blocks.INORGANIC CHEMISTRY,42(4),1130-1134.
MLA Zhang, WJ,et al."Double-stranded W/Ag/S chain structure generated from [syn-{WO(NCS)(2)}(2)(mu-S)(2)] building blocks".INORGANIC CHEMISTRY 42.4(2003):1130-1134.
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