ICCAS OpenIR
Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone
Xue, L; Li, BY; Huang, MY; Jiang, YY
2003-03-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume14Issue:3-5Pages:282-286
AbstractA new chiral polymer-metal complex, silica-supported alginic acid-L-glutamic acid-Pt complex (SiO2-AA-L-Glu-Pt), has been prepared by a very simple method and has been found to be able to catalyze the asymmetric hydrogenation of 4-methyl-2-pentanone to give (R)-(-)-4-methyl-2-pentanol in 90.8% optical yield at 30degreesC and under 1 atm H-2. The product and optical yields were greatly affected by the Pt content in the complex, the solvent, the 4-methyl-2-pentanone/Pt molar ratio and the reaction temperature. The catalyst could be reused several times without any great change in its optical catalytic activity. Copyright (C) 2003 John Wiley Sons, Ltd.
KeywordAlginic Acid L-glutamic Acid Pt Complex Catalyst 4-methyl-2-pentanone Asymmetric Hydrogenation
DOI10.1002/pat.307
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000182654500019
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81408
Collection中国科学院化学研究所
Corresponding AuthorXue, L
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Xue, L,Li, BY,Huang, MY,et al. Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2003,14(3-5):282-286.
APA Xue, L,Li, BY,Huang, MY,&Jiang, YY.(2003).Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone.POLYMERS FOR ADVANCED TECHNOLOGIES,14(3-5),282-286.
MLA Xue, L,et al."Preparation of silica-supported alginic acid-L-glutamic acid-Pt complex and its catalytic behaviors in asymmetric hydrogenation of 4-methyl-2-pentanone".POLYMERS FOR ADVANCED TECHNOLOGIES 14.3-5(2003):282-286.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Xue, L]'s Articles
[Li, BY]'s Articles
[Huang, MY]'s Articles
Baidu academic
Similar articles in Baidu academic
[Xue, L]'s Articles
[Li, BY]'s Articles
[Huang, MY]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Xue, L]'s Articles
[Li, BY]'s Articles
[Huang, MY]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.