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Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage
Xing, XP; Liu, HT; Tang, ZC
2003-04-22
Source PublicationPHYSCHEMCOMM
ISSN1460-2733
Volume6Pages:32-35
AbstractThis article reports on the generation of [M-m-phenyl](-) (M = Mn-Cu) complexes, which are very rare cases in chemistry. Experimental results showed that the typical cation products for the reactions of all 3d transition metal clusters (Sc-Cu) with benzene were different [M-m(C6H6)(n)](+) (M = Sc-Cu) species, while the typical anion products for the late 3d transition metals were [M-m-C6H5](-) (M = Mn-Cu) complexes. Their formation mechanisms, which involve anion metal clusters inducing a selective benzene C - H cleavage in the gas phase, were proposed.
DOI10.1039/b302761a
Indexed BySCI
Language英语
WOS IDWOS:000182473600001
PublisherROYAL SOC CHEMISTRY
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81290
Collection中国科学院化学研究所
Corresponding AuthorXing, XP
AffiliationChinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Xing, XP,Liu, HT,Tang, ZC. Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage[J]. PHYSCHEMCOMM,2003,6:32-35.
APA Xing, XP,Liu, HT,&Tang, ZC.(2003).Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage.PHYSCHEMCOMM,6,32-35.
MLA Xing, XP,et al."Generation of [M-m-phenyl](-) (M = Mn-Cu) complexes in the gas phase: Metal cluster anions inducement of a selective benzene C-H cleavage".PHYSCHEMCOMM 6(2003):32-35.
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