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Mixed molybdenum-vanadium polyoxoanion-bridged trimetallic nanocluster complexes: Hydrothermal syntheses and crystal structures of {(Mo6Mo2V8O40-)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(2)(H2O)](2)}[Co-2(phen)(2)(OH)(2)(H2O)(4)](1/2) and {(Mo5Mo3V8O40)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(en)(H2O)](2)}[Co(phen )(3)]center dot 1.5H(2)O
Liu, CM; Zhang, DQ; Zhu, DB
2003-05-01
Source PublicationCRYSTAL GROWTH & DESIGN
ISSN1528-7483
Volume3Issue:3Pages:363-368
AbstractTwo novel trimetallic nanocluster complexes, {(Mo6Mo2V8O40)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(2)(H2O)](2)}[Co-2-(phen)(2)(OH)(2)(H2O)(4)](1/2) (1) (phen = 1,10'-phenanthroline) and {(Mo5Mo3V8O40)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(en)(H2O)](2)}[Co(phen)(3)] . 1.5H(2)O (2) (phen = 1,10'-phenanthroline, en = ethylenediamine), which are the first examples of mixed molybdenum-vanadium polyoxoanion bridged cluster complexes, have been hydrothermally prepared and characterized by X-ray crystallography.
DOI10.1021/cg0200715
Indexed BySCI
Language英语
WOS IDWOS:000182984500011
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:97[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81136
Collection中国科学院化学研究所
Corresponding AuthorLiu, CM
AffiliationChinese Acad Sci, Organ Solids Lab, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, CM,Zhang, DQ,Zhu, DB. Mixed molybdenum-vanadium polyoxoanion-bridged trimetallic nanocluster complexes: Hydrothermal syntheses and crystal structures of {(Mo6Mo2V8O40-)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(2)(H2O)](2)}[Co-2(phen)(2)(OH)(2)(H2O)(4)](1/2) and {(Mo5Mo3V8O40)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(en)(H2O)](2)}[Co(phen )(3)]center dot 1.5H(2)O[J]. CRYSTAL GROWTH & DESIGN,2003,3(3):363-368.
APA Liu, CM,Zhang, DQ,&Zhu, DB.(2003).Mixed molybdenum-vanadium polyoxoanion-bridged trimetallic nanocluster complexes: Hydrothermal syntheses and crystal structures of {(Mo6Mo2V8O40-)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(2)(H2O)](2)}[Co-2(phen)(2)(OH)(2)(H2O)(4)](1/2) and {(Mo5Mo3V8O40)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(en)(H2O)](2)}[Co(phen )(3)]center dot 1.5H(2)O.CRYSTAL GROWTH & DESIGN,3(3),363-368.
MLA Liu, CM,et al."Mixed molybdenum-vanadium polyoxoanion-bridged trimetallic nanocluster complexes: Hydrothermal syntheses and crystal structures of {(Mo6Mo2V8O40-)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(2)(H2O)](2)}[Co-2(phen)(2)(OH)(2)(H2O)(4)](1/2) and {(Mo5Mo3V8O40)-Mo-VI-V-V-O-IV(PO4)[Co(phen)(en)(H2O)](2)}[Co(phen )(3)]center dot 1.5H(2)O".CRYSTAL GROWTH & DESIGN 3.3(2003):363-368.
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