ICCAS OpenIR
Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene
Xue, H; Xu, YA; Ding, JY; Gao, LX; Ding, MX
2003-09-01
Source PublicationPOLYMER INTERNATIONAL
ISSN0959-8103
Volume52Issue:9Pages:1423-1427
AbstractAtom transfer radical polymerization (ATPP) of (R)-2-methacryloyloxy-2'-methoxy-1,1'-binaphthalene ((R)-MAMBN) mediated by different amine ligands, copper(l) chloride and ethyl 2-bromopropionate in different solvents, and reverse ATRP of (R)-MAMBN were studied. It was shown that optically active polymers were obtained, with poor control of the molecular weights, and low polydispersities. Specific rotation of the polymers increased with increasing molecular weights. By comparison with (R)-MAMBN, poly((R)-MAMBN)s exhibits higher specific rotation and a positive Cotton effect. (C) 2003 Society of Chemical Industry.
KeywordAtom Transfer Radical Polymerization Optically Active Polymer Specific Rotation 1 1 '-binaphthyl Moiety
DOI10.1002/pi.1236
Indexed BySCI
Language英语
WOS IDWOS:000185206400004
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81114
Collection中国科学院化学研究所
Corresponding AuthorDing, MX
AffiliationChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Xue, H,Xu, YA,Ding, JY,et al. Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene[J]. POLYMER INTERNATIONAL,2003,52(9):1423-1427.
APA Xue, H,Xu, YA,Ding, JY,Gao, LX,&Ding, MX.(2003).Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene.POLYMER INTERNATIONAL,52(9),1423-1427.
MLA Xue, H,et al."Atom transfer radical polymerization of (R)-2-methacryloyloxy-2 '-methoxy-1,1 '-binaphthalene".POLYMER INTERNATIONAL 52.9(2003):1423-1427.
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