ICCAS OpenIR
Hydrogenation of nitrobenzene, cyclohexanone and octene catalyzed by silica-supported starch-L-glutamic acid-Fe complex
Liu, HW; Huang, K; Mi, JD; Jia, Y; Huang, MY; Jiang, YY
2003-03-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume14Issue:3-5Pages:355-359
AbstractA new polymer-base metal complex, silica-supported starch-L-glutamic acid-Fe complex (SiO2-ST-Glu-Fe) has been prepared by a simple method. Starch was reacted with L-glutamic acid in the presence of silica to give a ligand SiO2-ST-Glu, then this was reacted with FeCl3.6H(2)O to form the Fe complex (SiO2-ST-Glu-Fe). The complex has been found to be able to catalyze the hydrogenation of nitrobenzene to give aniline in 100% yield, cyclohexanone to give cyclohexanol in 93% yield and octene to give octane in 84% yield at 45degreesC and under atmospheric pressure. Experimental data show that the catalyst was very stable and could be reused without any noticeable change in its catalytic activity. Copyright (C) 2003 John Wiley Sons, Ltd.
KeywordStarch Glutamic Acid Fe Complex Catalyst Hydrogenation Nitrobenzene
DOI10.1002/pat.320
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000182654500032
PublisherJOHN WILEY & SONS LTD
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81078
Collection中国科学院化学研究所
Corresponding AuthorLiu, HW
AffiliationChinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, HW,Huang, K,Mi, JD,et al. Hydrogenation of nitrobenzene, cyclohexanone and octene catalyzed by silica-supported starch-L-glutamic acid-Fe complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2003,14(3-5):355-359.
APA Liu, HW,Huang, K,Mi, JD,Jia, Y,Huang, MY,&Jiang, YY.(2003).Hydrogenation of nitrobenzene, cyclohexanone and octene catalyzed by silica-supported starch-L-glutamic acid-Fe complex.POLYMERS FOR ADVANCED TECHNOLOGIES,14(3-5),355-359.
MLA Liu, HW,et al."Hydrogenation of nitrobenzene, cyclohexanone and octene catalyzed by silica-supported starch-L-glutamic acid-Fe complex".POLYMERS FOR ADVANCED TECHNOLOGIES 14.3-5(2003):355-359.
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