ICCAS OpenIR
Preparations of pure ISeCN, ISCN, and INCO
Li, YM; Qiao, ZM; Sun, Q; Zhao, JC; Li, HY; Wang, DX
2003-12-15
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume42Issue:25Pages:8446-8448
AbstractPure INCO, ISCN, and the hitherto unknown molecule ISeCN have been prepared in the Hel photoelectron spectrometer (PES) by the heterogeneous reactions of ICI gas with AgNCO, AgSCN at room temperature, and AgSeCN at -9 (+/-1) degreesC, respectively. They were characterized on line by PES experiments and OVGF calculations. The well-matched results between the PES experiments and OVGF calculations not only show that the new reaction is a good reaction to prepare pure INCO and pure ISCN, but also that the new compound prepared by passing the ICI gas over the freshly AgSeCN powder at -9(+/-1) degreesC is the hitherto unknown ISeCN.
DOI10.1021/ic030158v
Indexed BySCI
Language英语
WOS IDWOS:000187162900040
PublisherAMER CHEMICAL SOC
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81042
Collection中国科学院化学研究所
Corresponding AuthorLi, HY
Affiliation1.Acad Sinica, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Li, YM,Qiao, ZM,Sun, Q,et al. Preparations of pure ISeCN, ISCN, and INCO[J]. INORGANIC CHEMISTRY,2003,42(25):8446-8448.
APA Li, YM,Qiao, ZM,Sun, Q,Zhao, JC,Li, HY,&Wang, DX.(2003).Preparations of pure ISeCN, ISCN, and INCO.INORGANIC CHEMISTRY,42(25),8446-8448.
MLA Li, YM,et al."Preparations of pure ISeCN, ISCN, and INCO".INORGANIC CHEMISTRY 42.25(2003):8446-8448.
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