ICCAS OpenIR
Nanoscale cavities for fulleropyrrolidinium in Nafion membrane
Li, JX; Zhang, S; Zhang, P; Liu, DF; Guo, ZX; Ye, C; Zhu, DB
2003-12-16
Source PublicationCHEMISTRY OF MATERIALS
ISSN0897-4756
Volume15Issue:25Pages:4739-4744
AbstractA general method was developed to incorporate fulleropyrrolidinium into the nanoscale cavities of Nafion membrane through electrostatic interaction. The aggregated sizes and structures of fulleropyrrolidinium were controlled by the cavities of Nafion membrane, which were confirmed by XPS and TEM studies. The incorporation was a diffusion-controlled process as evidenced from the absorption spectroscopic method. The absorption spectra of fulleropyrrolidinium nanoaggregates extended to the near-IR region and the fluorescence emission spectra were red-shifted due to the formation of excimers. The resulting fulleropyrrolidinium-Nafion nanocomposites exhibit significant optical-limiting effects at both 532 and 1064 nm, which imply their potential as broadband optical limiters to protect optical devices from damage by lasers.
DOI10.1021/cm034493t
Indexed BySCI
Language英语
WOS IDWOS:000187250800008
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/81020
Collection中国科学院化学研究所
Corresponding AuthorGuo, ZX
Affiliation1.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China
2.Acad Sinica, Grad Sch, Beijing 100080, Peoples R China
3.Hebei Univ Sci & Technol, Coll Sci, Shijiazhuang 050018, Peoples R China
Recommended Citation
GB/T 7714
Li, JX,Zhang, S,Zhang, P,et al. Nanoscale cavities for fulleropyrrolidinium in Nafion membrane[J]. CHEMISTRY OF MATERIALS,2003,15(25):4739-4744.
APA Li, JX.,Zhang, S.,Zhang, P.,Liu, DF.,Guo, ZX.,...&Zhu, DB.(2003).Nanoscale cavities for fulleropyrrolidinium in Nafion membrane.CHEMISTRY OF MATERIALS,15(25),4739-4744.
MLA Li, JX,et al."Nanoscale cavities for fulleropyrrolidinium in Nafion membrane".CHEMISTRY OF MATERIALS 15.25(2003):4739-4744.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Li, JX]'s Articles
[Zhang, S]'s Articles
[Zhang, P]'s Articles
Baidu academic
Similar articles in Baidu academic
[Li, JX]'s Articles
[Zhang, S]'s Articles
[Zhang, P]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Li, JX]'s Articles
[Zhang, S]'s Articles
[Zhang, P]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.