ICCAS OpenIR
New clusters in endohedral fullerenes: The metalnitrides
Dunsch, L; Georgi, P; Krause, M; Wang, CR
2003-04-04
Source PublicationSYNTHETIC METALS
ISSN0379-6779
Volume135Issue:1-3Pages:761-762
AbstractNew clusters in endohedral fullerenes can stabilize fullerene cages which are not to be isolated in the empty form like C-72 or C-74 and even the non-IPR structures C-66 and C-68. On the other hand fullerenes can provide an ideal isolated environment with its internal space, which enables the stabilization of clusters such as Sc2C2 (Sc2C2@C-84) or Sc3N (Sc3N@C-80). To open the route for new endohedral fullerene structures we report on the influence of the type of the atmosphere in the arc burning process as well as on new nitride cluster fullerenes like Ho3N@C-80. In this way a synthesis of fullerenes is described for the first time where the endohedral structures are the main product (yield in the range of 70 to 90 %) of all fullerenes. The isolated endohedral structures were studied spectroscopically as well as by cyclic voltammetry. The results of spectroscopic data were compared with the data for other endohedral fullerenes and the interactions of the clusters with cage are analysed. As a conclusion of the synthesis of new endohedral fullerenes by variation of the atmosphere in the burning chamber a general outlook of the potentialities of this new route in fullerene production is given.
KeywordEndohedral Fullerenes Clusters Scandium Holmium Uv-vis-nir Absorption Hplc
DOI10.1016/S0379-6779(02)00837-8
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000182533700358
PublisherELSEVIER SCIENCE SA
Citation statistics
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80984
Collection中国科学院化学研究所
Corresponding AuthorDunsch, L
Affiliation1.Leibnis Inst Festkorper & Werkstoffforsch, D-01069 Dresden, Germany
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.Nagoya Univ, Dept Chem, Nagoya, Aichi 4648602, Japan
Recommended Citation
GB/T 7714
Dunsch, L,Georgi, P,Krause, M,et al. New clusters in endohedral fullerenes: The metalnitrides[J]. SYNTHETIC METALS,2003,135(1-3):761-762.
APA Dunsch, L,Georgi, P,Krause, M,&Wang, CR.(2003).New clusters in endohedral fullerenes: The metalnitrides.SYNTHETIC METALS,135(1-3),761-762.
MLA Dunsch, L,et al."New clusters in endohedral fullerenes: The metalnitrides".SYNTHETIC METALS 135.1-3(2003):761-762.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Dunsch, L]'s Articles
[Georgi, P]'s Articles
[Krause, M]'s Articles
Baidu academic
Similar articles in Baidu academic
[Dunsch, L]'s Articles
[Georgi, P]'s Articles
[Krause, M]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Dunsch, L]'s Articles
[Georgi, P]'s Articles
[Krause, M]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.