ICCAS OpenIR
Preparation and characterization of poly(tetramethyl-p-phenylenediamine)/clay hybrids via intercalative polymerization
Chen, GM; Lyi, NB; Fujita, T
2003-02-01
Source PublicationJOURNAL OF MATERIALS RESEARCH
ISSN0884-2914
Volume18Issue:2Pages:482-486
AbstractNew noncovalent bonding polymer/clay hybrids were prepared, including the polymer poly(tetramethyl-p-phenylenediamine) (poly-TMPD). Polymerization occurred in the interlayer space of clay mineral successively after intercalation of monomers. Two types of clay minerals with different surface properties-a hydrophilic lithium fluorotaeniolite (TN) and four kinds of organophilic fluorotaeniolites (org-TNs)were used as the hosts. Powder x-ray diffraction results showed an increase of 0.7-1.0 nm in the basal spacings, indicating the formation of poly-TMPD in the interlayer space of the hosts. Intercalative polymerization was also supported by Fourier transform infrared spectroscopy. The orientation of the poly-TMPD and thermal behavior were also discussed.
Indexed BySCI
Language英语
WOS IDWOS:000180889900029
PublisherCAMBRIDGE UNIV PRESS
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80982
Collection中国科学院化学研究所
Corresponding AuthorChen, GM
Affiliation1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China
2.Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan
3.Natl Inst Mat Sci, Adv Mat Lab, Tsukuba, Ibaraki 3050044, Japan
Recommended Citation
GB/T 7714
Chen, GM,Lyi, NB,Fujita, T. Preparation and characterization of poly(tetramethyl-p-phenylenediamine)/clay hybrids via intercalative polymerization[J]. JOURNAL OF MATERIALS RESEARCH,2003,18(2):482-486.
APA Chen, GM,Lyi, NB,&Fujita, T.(2003).Preparation and characterization of poly(tetramethyl-p-phenylenediamine)/clay hybrids via intercalative polymerization.JOURNAL OF MATERIALS RESEARCH,18(2),482-486.
MLA Chen, GM,et al."Preparation and characterization of poly(tetramethyl-p-phenylenediamine)/clay hybrids via intercalative polymerization".JOURNAL OF MATERIALS RESEARCH 18.2(2003):482-486.
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