ICCAS OpenIR
Hydration of alkenes catalyzed by wool-palladium-iron complex
Jia, B; Yang, X; Huang, MY; Jiang, YY
2003
Source PublicationREACTIVE & FUNCTIONAL POLYMERS
ISSN1381-5148
Volume57Issue:2-3Pages:163-168
AbstractA new biopolymer-metal complex, wool-supported palladium-iron complex (wool-Pd-Fe), has been prepared and found to be a highly active catalyst for hydration of some alkenes to corresponding alcohols, such as allyl bromide to 1-bromo-2-propanol, allyl chloride to 1-chloro-2-propanol, allylamine to 1-amino-2-propanol, acrylonitrile to lactonitrile and cyclohexene to cyclohexanol in 95.0%, 87.5%, 90.6%, 75.3% and 98.2% yield, respectively, in the presence of water, butyl ether and phenol at 95 degreesC under 1 atm N-2. The yield was greatly affected by the Pd/Fe molar ratio in wool-Pd-Fe complex catalyst. And this catalyst was very stable and could be reused several times without remarkable change in the catalytic activity. (C) 2003 Elsevier B.V. All rights reserved.
KeywordBiopolymer Wool-palladium-iron Complex Catalyst Hydration Alkenes Alcohols
DOI10.1016/j.reactfunctpolym.2003.08.006
Indexed BySCI
Language英语
WOS IDWOS:000187666500010
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80976
Collection中国科学院化学研究所
Corresponding AuthorJia, B
AffiliationChinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Jia, B,Yang, X,Huang, MY,et al. Hydration of alkenes catalyzed by wool-palladium-iron complex[J]. REACTIVE & FUNCTIONAL POLYMERS,2003,57(2-3):163-168.
APA Jia, B,Yang, X,Huang, MY,&Jiang, YY.(2003).Hydration of alkenes catalyzed by wool-palladium-iron complex.REACTIVE & FUNCTIONAL POLYMERS,57(2-3),163-168.
MLA Jia, B,et al."Hydration of alkenes catalyzed by wool-palladium-iron complex".REACTIVE & FUNCTIONAL POLYMERS 57.2-3(2003):163-168.
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