ICCAS OpenIR
High pressure effect on the intramolecular electron transfer process
He, LM; Li, H; Fan, JF; Li, SY; Gan, Q; Zhang, GQ; Zhang, BW; Li, Y; Yang, GQ
2003-09-05
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume378Issue:3-4Pages:263-268
AbstractAn intramolecular electron transfer compound (4-(10-cyano-9-anthracenylmethyl)-NN-dimethylaniline) has been studied under different pressure up to about 6 GPa. The electron transfer (ET) rate constants (k(et)) with pressure have been obtained from its fluorescence emission and decay processes at different pressures. By analogy with the theory of optical transition, the free energy change (DeltaG) and solvent reorganization energy (lambda) during the ET process can be expressed by the functions including the variable pressure. The experimental results can be understood well by analyzing the influence of DeltaG and lambda on the k(et) with pressure. (C) 2003 Elsevier B.V. All rights reserved.
DOI10.1016/S0009-2614(03)01335-6
Indexed BySCI
Language英语
WOS IDWOS:000185368300007
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80958
Collection中国科学院化学研究所
Corresponding AuthorLi, Y
Affiliation1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
He, LM,Li, H,Fan, JF,et al. High pressure effect on the intramolecular electron transfer process[J]. CHEMICAL PHYSICS LETTERS,2003,378(3-4):263-268.
APA He, LM.,Li, H.,Fan, JF.,Li, SY.,Gan, Q.,...&Yang, GQ.(2003).High pressure effect on the intramolecular electron transfer process.CHEMICAL PHYSICS LETTERS,378(3-4),263-268.
MLA He, LM,et al."High pressure effect on the intramolecular electron transfer process".CHEMICAL PHYSICS LETTERS 378.3-4(2003):263-268.
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