ICCAS OpenIR
Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods
Xue, H; Xu, YA; Song, NH; Gao, LX; Ding, MX
2003-08-01
Source PublicationPOLYMER INTERNATIONAL
ISSN0959-8103
Volume52Issue:8Pages:1321-1325
AbstractOptically active and racemic poly(meth)acrylates with pendant 1,1'-binaphthalene moiety of 2-methacryloyloxy- and 2-acryloyloxy-2'-methoxy-1,1'-binaphthalene (MAMBN and AMBN) were synthesized by anionic, group transfer and free radical polymerization methods. Their polymerizability and chiroptical properties are somewhat different, depending on the three types of polymerization methods used. The yields for poly(MAMBN)s are lower than for poly(AMBN)s. The optical rotation of the optically active polymers is identical to that of the corresponding monomers. The values of specific rotation of optically active poly(AMBN)s are much larger than those of optically active poly(MAMBN)s. (C) 2002 Society of Chemical Industry.
KeywordAnionic Polymerization Group Transfer Polymerization Free Radical Polymerization Optically Active Polymer
DOI10.1002/pi.980
Indexed BySCI
Language英语
WOS IDWOS:000184478600013
PublisherJOHN WILEY & SONS LTD
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80910
Collection中国科学院化学研究所
Corresponding AuthorDing, MX
AffiliationChinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Recommended Citation
GB/T 7714
Xue, H,Xu, YA,Song, NH,et al. Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods[J]. POLYMER INTERNATIONAL,2003,52(8):1321-1325.
APA Xue, H,Xu, YA,Song, NH,Gao, LX,&Ding, MX.(2003).Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods.POLYMER INTERNATIONAL,52(8),1321-1325.
MLA Xue, H,et al."Study of optically active methacrylates containing 1,1 '-binaphthyl side-groups polymerized by anionic, group transfer and free radical methods".POLYMER INTERNATIONAL 52.8(2003):1321-1325.
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