ICCAS OpenIR
Synthesis of chiral binaphthyl crown ethers and their use in anionic polymerization of methyl methacrylate as initiator ligands
Liu, HW; Chen, CF; Xi, F
2003-12-01
Source PublicationCHINESE JOURNAL OF POLYMER SCIENCE
ISSN0256-7679
Volume22Issue:1Pages:63-68
AbstractSome chiral binaphthyl crown ethers were synthesized. The anionic polymerization of methyl methacrylate (MMA) was carried out in the presence of t-BuOK, Ph2CHK or Ph2CHNa (RM), and RM coordination initiator by using chiral binaphthyl crown ethers as ligands, respectively. The results showed that in the former case the PMMA obtained has mainly isotactic structure but without optical activity, while in the later case the PMMA produced predominately has syndiotactic structure also without optical activity.
KeywordChiral Binaphthyl Crown Ether Mma Anionic Polymerization
Indexed BySCI
Language英语
WOS IDWOS:000188355900009
PublisherSPRINGER-VERLAG HEIDELBERG
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80894
Collection中国科学院化学研究所
Corresponding AuthorXi, F
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, HW,Chen, CF,Xi, F. Synthesis of chiral binaphthyl crown ethers and their use in anionic polymerization of methyl methacrylate as initiator ligands[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2003,22(1):63-68.
APA Liu, HW,Chen, CF,&Xi, F.(2003).Synthesis of chiral binaphthyl crown ethers and their use in anionic polymerization of methyl methacrylate as initiator ligands.CHINESE JOURNAL OF POLYMER SCIENCE,22(1),63-68.
MLA Liu, HW,et al."Synthesis of chiral binaphthyl crown ethers and their use in anionic polymerization of methyl methacrylate as initiator ligands".CHINESE JOURNAL OF POLYMER SCIENCE 22.1(2003):63-68.
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