ICCAS OpenIR
Oxidative carbonylation of methanol to dimethyl carbonate in ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate
Jiang, T; Han, BX; Zhao, GY; Chang, YH; Gao, L; Zhang, JM; Yang, GY
2003-09-01
Source PublicationJOURNAL OF CHEMICAL RESEARCH-S
ISSN0308-2342
Issue9Pages:549-551
AbstractThe synthesis of dimethyl carbonate (DMC) by oxidative carbonylation of methanol with PdCl2 as a catalyst was investigated in the room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]). The products were recovered in situ using supercritical carbon dioxide. Enhanced selectivity of DMC over this catalyst was observed in the synthesis in [bmim][PF6] compared with the situation without the ionic liquid (IL). The mixture of catalyst and [bmim][PF6] could be recycled.
KeywordIonic Liquids Dimethyl Carbonate Methanol Oxidative Carbonylation
Indexed BySCI ; CCR
Language英语
WOS IDWOS:000187797400011
PublisherSCIENCE REVIEWS LTD
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80868
Collection中国科学院化学研究所
Corresponding AuthorHan, BX
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Jiang, T,Han, BX,Zhao, GY,et al. Oxidative carbonylation of methanol to dimethyl carbonate in ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate[J]. JOURNAL OF CHEMICAL RESEARCH-S,2003(9):549-551.
APA Jiang, T.,Han, BX.,Zhao, GY.,Chang, YH.,Gao, L.,...&Yang, GY.(2003).Oxidative carbonylation of methanol to dimethyl carbonate in ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate.JOURNAL OF CHEMICAL RESEARCH-S(9),549-551.
MLA Jiang, T,et al."Oxidative carbonylation of methanol to dimethyl carbonate in ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate".JOURNAL OF CHEMICAL RESEARCH-S .9(2003):549-551.
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