ICCAS OpenIR
Studies on the silicone resins cured with polymethylsilazanes at ambient temperature
Zhang, YM; Huang, Y; Liu, XL; Yu, YZ
2003-08-08
Source PublicationJOURNAL OF APPLIED POLYMER SCIENCE
ISSN0021-8995
Volume89Issue:6Pages:1702-1707
AbstractPolymethylsilazanes (PMS) were synthesized and used to cure silicone resins at ambient temperature. The curing degree of the silicone resins depends on the structure of PMS, and its concentration in the resin. Silicone resins of different structure and different silanol content can be cured to a satisfactory degree, if the concentration of the PMS is high enough. Silicone resins cured with PMS showed improved thermal stability in nitrogen, compared with that of the heat-cured counterparts. The mechanism of thermal decomposition of the silicone resins is discussed. The improvement of heat resistance using PMS as the curing agent is accounted for by diminished thermal rearrangement and degradation of the polysiloxane network initiated by silanol groups in the resins. (C) 2003 Wiley Periodicals, Inc.
KeywordSilicones Curing Of Polymers Thermal Properties Polymethylsilazanes Resins
DOI10.1002/app.12433
Indexed BySCI
Language英语
WOS IDWOS:000183355800036
PublisherJOHN WILEY & SONS INC
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80738
Collection中国科学院化学研究所
Corresponding AuthorHuang, Y
AffiliationChinese Acad Sci, Inst Chem, Natl Key Lab Engn Plast, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Zhang, YM,Huang, Y,Liu, XL,et al. Studies on the silicone resins cured with polymethylsilazanes at ambient temperature[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2003,89(6):1702-1707.
APA Zhang, YM,Huang, Y,Liu, XL,&Yu, YZ.(2003).Studies on the silicone resins cured with polymethylsilazanes at ambient temperature.JOURNAL OF APPLIED POLYMER SCIENCE,89(6),1702-1707.
MLA Zhang, YM,et al."Studies on the silicone resins cured with polymethylsilazanes at ambient temperature".JOURNAL OF APPLIED POLYMER SCIENCE 89.6(2003):1702-1707.
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