ICCAS OpenIR
Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex
Miao, JH; Yang, JH; Chen, LY; Huang, MY; Jiang, YY
2003-10-01
Source PublicationCHINESE CHEMICAL LETTERS
ISSN1001-8417
Volume14Issue:10Pages:1008-1011
AbstractA new chiral polymer-metal complex, wool-osmium tetroxide(wool-OsO4) complex was prepared by a very simple method. This complex was found to be able to catalyze the asymmetric dihydroxylation of allylamine to get (R)-(+)-3-amino-1, 2-propanediol. The experimental results showed that OsO4 content in the complex, reaction time, allylamine/OsO4 molar ratio all have great effects on the chemical and optical yields of product. Additionally, wool-OsO4 complex catalyst could be reused without remarkable change in optical catalytic activity.
KeywordWool-osmium Tetroxide Asymmetric Dihydroxylation Allylamine
Indexed BySCI
Language英语
WOS IDWOS:000185983600007
PublisherCHINESE CHEMICAL SOCIETY
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80704
Collection中国科学院化学研究所
Corresponding AuthorMiao, JH
Affiliation1.Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Peoples R China
2.Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Miao, JH,Yang, JH,Chen, LY,et al. Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex[J]. CHINESE CHEMICAL LETTERS,2003,14(10):1008-1011.
APA Miao, JH,Yang, JH,Chen, LY,Huang, MY,&Jiang, YY.(2003).Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex.CHINESE CHEMICAL LETTERS,14(10),1008-1011.
MLA Miao, JH,et al."Asymmetric dihydroxylation of allylamine catalyzed by Wool-OsO4 complex".CHINESE CHEMICAL LETTERS 14.10(2003):1008-1011.
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