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Hydrothermal synthesis and crystal structure of a new alpha-Keggin unit-supported cobalt bipyridyl complex: [Co(2,2 '-bipy)(3)](1.5)[SiW12O40Co(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O
Liu, CM; Huang, YH; Zhang, DQ; Jiang, FC; Zhu, DB
2003-07-20
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume56Issue:11Pages:953-960
AbstractA new alpha-Keggin unit-supported transition metal complex [Co(2,2'-bipy)(3)](1.5)[SiW12O40Co(2,2'-bipy)(2)(H2O)].0.5H(2)O has been hydrothermally synthesized and characterized by X-ray crystallography, showing that [Co(2,2'-bipy)(2)(H2O)](2+) units are covalently bonded to the alpha-Keggin cluster [(SiWW11O50)-W-V-O-VI](5-). Intermolecular hydrogen bonding interactions and short O ... O contacts force the structure into an interesting one-dimensional suprarmolecular array. Crystals are monoclinic space group C2/c, with a = 46.676(9), b = 14.348(3), c = 26.010(5) Angstrom, beta = 90.33(3)degrees, V = 17419(6) Angstrom(3), Z = 8.
KeywordHydrothermal Synthesis Cobalt(Ii) Cluster Complex Crystal Structure Polyoxoanion Complex Keggin Ion
DOI10.1080/0095897031000135342
Indexed BySCI
Language英语
WOS IDWOS:000185480500004
PublisherTAYLOR & FRANCIS LTD
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80638
Collection中国科学院化学研究所
Corresponding AuthorLiu, CM
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China
2.Jiangxi Normal Univ, Dept Chem, Nanchang 210027, Peoples R China
Recommended Citation
GB/T 7714
Liu, CM,Huang, YH,Zhang, DQ,et al. Hydrothermal synthesis and crystal structure of a new alpha-Keggin unit-supported cobalt bipyridyl complex: [Co(2,2 '-bipy)(3)](1.5)[SiW12O40Co(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O[J]. JOURNAL OF COORDINATION CHEMISTRY,2003,56(11):953-960.
APA Liu, CM,Huang, YH,Zhang, DQ,Jiang, FC,&Zhu, DB.(2003).Hydrothermal synthesis and crystal structure of a new alpha-Keggin unit-supported cobalt bipyridyl complex: [Co(2,2 '-bipy)(3)](1.5)[SiW12O40Co(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O.JOURNAL OF COORDINATION CHEMISTRY,56(11),953-960.
MLA Liu, CM,et al."Hydrothermal synthesis and crystal structure of a new alpha-Keggin unit-supported cobalt bipyridyl complex: [Co(2,2 '-bipy)(3)](1.5)[SiW12O40Co(2,2 '-bipy)(2)(H2O)]center dot 0.5H(2)O".JOURNAL OF COORDINATION CHEMISTRY 56.11(2003):953-960.
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