ICCAS OpenIR
Synthesis and crystal structures of novel beta-diketiminato-lithium, iron, cobalt, nickel, zirconium complexes and their catalytical behaviors in polymerization of ethylene
Zhou, MS; Huang, SP; Weng, LH; Sun, WH; Liu, DS
2003-01-03
Source PublicationJOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN0022-328X
Volume665Issue:1-2Pages:237-245
AbstractTreatment of azaallyl-lithium [LiN(R)C(Bu-t)CHR] with equal portion of 1-piperidinecarbonitrile gave mix-substituted beta-diketiminato-lithium 2. Double ratio of 2 with FeCl2, CoCl2 and NiCl2.6H(2)O yielded the beta-diketiminate iron 3, cobalt 4, nickel 5, or equivalent of ZrCl4 led to zirconium complex 6, respectively. The structural features of these complexes were described, and the catalytical behaviors of the complexes 3-6 for the polymerization of ethylene were investigated. (C) 2002 Elsevier Science B.V. All rights reserved.
KeywordBeta-diketiminate Crystal Structures Catalysis Zirconium Transition Metal
Indexed BySCI ; IC
Language英语
WOS IDWOS:000180689100032
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:49[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80490
Collection中国科学院化学研究所
Corresponding AuthorLiu, DS
Affiliation1.Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Peoples R China
2.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
3.Chinese Acad Sci, State Key Lab Engn Plast, Beijing, Peoples R China
4.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Zhou, MS,Huang, SP,Weng, LH,et al. Synthesis and crystal structures of novel beta-diketiminato-lithium, iron, cobalt, nickel, zirconium complexes and their catalytical behaviors in polymerization of ethylene[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2003,665(1-2):237-245.
APA Zhou, MS,Huang, SP,Weng, LH,Sun, WH,&Liu, DS.(2003).Synthesis and crystal structures of novel beta-diketiminato-lithium, iron, cobalt, nickel, zirconium complexes and their catalytical behaviors in polymerization of ethylene.JOURNAL OF ORGANOMETALLIC CHEMISTRY,665(1-2),237-245.
MLA Zhou, MS,et al."Synthesis and crystal structures of novel beta-diketiminato-lithium, iron, cobalt, nickel, zirconium complexes and their catalytical behaviors in polymerization of ethylene".JOURNAL OF ORGANOMETALLIC CHEMISTRY 665.1-2(2003):237-245.
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