ICCAS OpenIR
Dendritic BINAP based system for asymmetric hydrogenation of simple aryl ketones
Deng, GJ; Fan, QH; Chen, XM; Liu, GH
2003-02-17
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN1381-1169
Volume193Issue:1-2Pages:21-25
AbstractA series of dendritic BINAP-Ru/chiral diamine catalysts were developed for asymmetric hydrogenation of various simple aryl ketones. The resulting catalytic system showed very attractive due to very good catalytic activity and enantioselectivity as well as facile catalyst recycling. In the case of 1-acetonaphthone and 2'-methyl-acetophenone, interesting e.e. value up to 95% was observed which are comparable to the enantioselectivity reported by Noyori under similar conditions and higher than that of the heterogeneous poly(BINAP)-Ru catalyst reported by Pu and co-workers [Tetrahedron Lett. 41 (2000) 1681]. (C) 2002 Elsevier Science B.V. All rights reserved.
KeywordAsymmetric Hydrogenation Dendritic Catalyst Binap Dpen Chiral Secondary Alcohol
Indexed BySCI
Language英语
WOS IDWOS:000181527300003
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:39[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80486
Collection中国科学院化学研究所
Corresponding AuthorFan, QH
Affiliation1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
2.Nankai Univ, State Key Lab Elemental Organ Chem, Tianjin 300071, Peoples R China
Recommended Citation
GB/T 7714
Deng, GJ,Fan, QH,Chen, XM,et al. Dendritic BINAP based system for asymmetric hydrogenation of simple aryl ketones[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2003,193(1-2):21-25.
APA Deng, GJ,Fan, QH,Chen, XM,&Liu, GH.(2003).Dendritic BINAP based system for asymmetric hydrogenation of simple aryl ketones.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,193(1-2),21-25.
MLA Deng, GJ,et al."Dendritic BINAP based system for asymmetric hydrogenation of simple aryl ketones".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 193.1-2(2003):21-25.
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