ICCAS OpenIR
High-resolution photofragment translational spectra of the photodissociation of CF3I at 248 nm
Wang, X; Tian, ZX; Shi, TJ; Shi, XH; Yang, DL; Zhu, QH
2003-10-28
Source PublicationCHEMICAL PHYSICS LETTERS
ISSN0009-2614
Volume380Issue:5-6Pages:600-603
AbstractThe photodissociation of CF3I at 248 nm was performed on our high-resolution photofragment translational spectrometer. For further improvement of the resolution, we have taken the following procedures: (1) Kr was used as carrier gas, (2) optimum molecular beam angle theta(opt) (when V-MB 1 V-CM) was selected, (3) the longitudinal molecular beam angle spread was reduced, and (4) the ionization region for photofragments was diminished. The photofragment translational spectra of I (P-2(1/2)) reveal eight well-resolved vibrational peaks. The highest peak was assigned to be v(2) = 5 of the v(2) vibrational mode, and then the dissociation energy would be D-0 (C-I) = 18 810 +/- 200 cm(-1) = 53.8 +/- 0.6 kcal/mol. (C) 2003 Elsevier B.V. All rights reserved.
DOI10.1016/j.cplett.2003.07.027
Indexed BySCI
Language英语
WOS IDWOS:000186265500019
PublisherELSEVIER SCIENCE BV
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80478
Collection中国科学院化学研究所
Corresponding AuthorZhu, QH
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Wang, X,Tian, ZX,Shi, TJ,et al. High-resolution photofragment translational spectra of the photodissociation of CF3I at 248 nm[J]. CHEMICAL PHYSICS LETTERS,2003,380(5-6):600-603.
APA Wang, X,Tian, ZX,Shi, TJ,Shi, XH,Yang, DL,&Zhu, QH.(2003).High-resolution photofragment translational spectra of the photodissociation of CF3I at 248 nm.CHEMICAL PHYSICS LETTERS,380(5-6),600-603.
MLA Wang, X,et al."High-resolution photofragment translational spectra of the photodissociation of CF3I at 248 nm".CHEMICAL PHYSICS LETTERS 380.5-6(2003):600-603.
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