ICCAS OpenIR
Effect of antisolvent carbon dioxide on the polymerization of methyl methacrylate in different solvents
Liu, J; Han, BX; Zhang, R; Liu, ZM; Jiang, T; Yang, GY
2003
Source PublicationJOURNAL OF SUPERCRITICAL FLUIDS
ISSN0896-8446
Volume25Issue:1Pages:91-97
AbstractPolymerization of methyl methacrylate (MMA) in chloroform (CF), ethyl acetate (EA), and iso-amyl acetate (iAA) with compressed CO2 as antisolvent has been carried out at 333.2 K and different monomer concentrations. The results show that at the low monomer concentration (1 mol l(-1)) the addition of the antisolvent CO2 reduces the yield and the molecular weight of the poly(methyl methacrylate) (PMMA). At the higher monomer concentration (4 mol l(-1)) the yield decreases initially, and then increases With the increase of CO2 pressure or the volume expansion ratio (VER) of the solution. The molecular weight and the molecular weight distribution of the products also vary with VER. (C) 2002 Elsevier Science B.V. All rights reserved.
KeywordPolymerization Antisolvent Methyl Methacrylate Co2
Indexed BySCI
Language英语
WOS IDWOS:000180592900009
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80470
Collection中国科学院化学研究所
Corresponding AuthorHan, BX
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Liu, J,Han, BX,Zhang, R,et al. Effect of antisolvent carbon dioxide on the polymerization of methyl methacrylate in different solvents[J]. JOURNAL OF SUPERCRITICAL FLUIDS,2003,25(1):91-97.
APA Liu, J,Han, BX,Zhang, R,Liu, ZM,Jiang, T,&Yang, GY.(2003).Effect of antisolvent carbon dioxide on the polymerization of methyl methacrylate in different solvents.JOURNAL OF SUPERCRITICAL FLUIDS,25(1),91-97.
MLA Liu, J,et al."Effect of antisolvent carbon dioxide on the polymerization of methyl methacrylate in different solvents".JOURNAL OF SUPERCRITICAL FLUIDS 25.1(2003):91-97.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, J]'s Articles
[Han, BX]'s Articles
[Zhang, R]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, J]'s Articles
[Han, BX]'s Articles
[Zhang, R]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, J]'s Articles
[Han, BX]'s Articles
[Zhang, R]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.