ICCAS OpenIR
Tubular poly(ortho-toluidine) synthesized by a template-free method
Wan, MX; Li, JC
2003-03-01
Source PublicationPOLYMERS FOR ADVANCED TECHNOLOGIES
ISSN1042-7147
Volume14Issue:3-5Pages:320-325
AbstractMicrotubules of poly(ortho-toluidine) (POT), with 0.8-6.0 mum diameter and 10(-4)-10(-2) S/cm room-temperature conductivity, were synthesized by a template-free method in the presence of beta-naphthalene sulfonic acid (beta-NSA) as a dopant. It was found that the completeness, size, room-temperature conductivity and crystallinity of the resulting POT-NSA microtubules depended upon the concentration of the NSA dopant. UV-vis. spectra, XPS and X-ray diffraction were used to characterize the molecular structure, showing that the polymer chain of POT-NSA microtubules is identical to that of the doped POT synthesized by a common method, but that its crystallinity is higher than that Of common POT. It was proposed that the monomer saltformed with NSA played a template-like role informing POT-NSA microtubules. Copyright (C) 2003 John Wiley Sons, Ltd.
KeywordPoly(Ortho-toluidine) Template-free Method Beta-naphthalene Sulfonic Acid Microtubes
DOI10.1002/pat.314
Indexed ByISTP ; SCI
Language英语
WOS IDWOS:000182654500026
PublisherJOHN WILEY & SONS LTD
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Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80390
Collection中国科学院化学研究所
Corresponding AuthorWan, MX
AffiliationChinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solid Lab, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Wan, MX,Li, JC. Tubular poly(ortho-toluidine) synthesized by a template-free method[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2003,14(3-5):320-325.
APA Wan, MX,&Li, JC.(2003).Tubular poly(ortho-toluidine) synthesized by a template-free method.POLYMERS FOR ADVANCED TECHNOLOGIES,14(3-5),320-325.
MLA Wan, MX,et al."Tubular poly(ortho-toluidine) synthesized by a template-free method".POLYMERS FOR ADVANCED TECHNOLOGIES 14.3-5(2003):320-325.
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