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Synthesis, structure and conductivity of (PyH)[Ni(dmit)(2)](2)
Xu, W; Fang, Q; Xue, G; Yu, WT; Chen, HY; Liu, GQ; Xu, W; Xu, CY; Zhang, DQ; Zhu, DB
2003-10-01
Source PublicationCHINESE CHEMICAL LETTERS
ISSN1001-8417
Volume14Issue:10Pages:1089-1092
AbstractA new molecular conductor (PyH)[Ni(dmit)(2)](2) (dmit = 4, 5-dimercapto-1, 3-dithiole-2-thione) has been prepared and its crystal structure has been determined. Crystallographic parameters for (PyH)[Ni(dmit)(2)](2): C17H6NNi2S20; triclinic system; P-I space group; a 5.9227 (4), b = 8.2279 (6), c = 16.7535 (9) Angstrom, alpha = 90.233 (5)degrees, beta = 92.107 (6)degrees, gamma = 104.654 (6)degrees; V = 789.25 (9) Angstrom(3); Z = 1; D-c = 2.068 g/cm(3);F(000) = 491. The conductivity atone direction on (001) plane at room temperature was measured to be 0.13 Omega(-1).cm(-1). The resistivity-temperature curve in the temperature range of 90similar to290 K shows that this compound behaves as a semiconductor.
KeywordMolecular Conductor Synthesis Electrical Conductivity Semiconductor Structure
Indexed BySCI
Language英语
WOS IDWOS:000185983600030
PublisherCHINESE CHEMICAL SOCIETY
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.iccas.ac.cn/handle/121111/80334
Collection中国科学院化学研究所
Corresponding AuthorXu, W; Xu, W
Affiliation1.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
Recommended Citation
GB/T 7714
Xu, W,Fang, Q,Xue, G,et al. Synthesis, structure and conductivity of (PyH)[Ni(dmit)(2)](2)[J]. CHINESE CHEMICAL LETTERS,2003,14(10):1089-1092.
APA Xu, W.,Fang, Q.,Xue, G.,Yu, WT.,Chen, HY.,...&Zhu, DB.(2003).Synthesis, structure and conductivity of (PyH)[Ni(dmit)(2)](2).CHINESE CHEMICAL LETTERS,14(10),1089-1092.
MLA Xu, W,et al."Synthesis, structure and conductivity of (PyH)[Ni(dmit)(2)](2)".CHINESE CHEMICAL LETTERS 14.10(2003):1089-1092.
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